Enantioselective Conjugate Borylation

Learn your ABCs! The asymmetric borylation in conjugate fashion has rapidly progressed in recent years if not months (see scheme, pin=pinacolato, TM=transition metal). This Highlight summarizes these breathtaking developments, including a mechanistic analysis. An outlook onto a future asymmetric org...

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Bibliographic Details
Published in:Angewandte Chemie (International ed.) 2010-02, Vol.49 (7), p.1194-1196
Main Authors: Schiffner, Julia A, Müther, Kristine, Oestreich, Martin
Format: Article
Language:English
Subjects:
asymmetric catalysis
boron
conjugate addition
copper
main group chemistry
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Summary:Learn your ABCs! The asymmetric borylation in conjugate fashion has rapidly progressed in recent years if not months (see scheme, pin=pinacolato, TM=transition metal). This Highlight summarizes these breathtaking developments, including a mechanistic analysis. An outlook onto a future asymmetric organocatalysis is presented as well.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.200906521