Assembly of Substituted Phenothiazines by a Sequentially Controlled CuI/ L-Proline-Catalyzed Cascade C----S and C----N Bond Formation

In the pro‐line of fire: A general and efficient cascade reaction approach to substituted phenothiazines, which relies on controlled sequential CuI/L‐proline‐catalyzed CS and CN bond formations, is described. DMSO=dimethylsulfoxide.

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Bibliographic Details
Published in:Angewandte Chemie (International ed.) 2010-02, Vol.49 (7), p.1291-1294
Main Authors: Ma, Dawei, Geng, Qian, Zhang, Hui, Jiang, Yongwen
Format: Article
Language:English
Subjects:
Aniline Compounds - chemistry
Carbon - chemistry
Catalysis
copper
Copper - chemistry
cross-coupling
heterocycles
homogeneous catalysis
Iodine - chemistry
Phenols - chemistry
phenothiazines
Phenothiazines - chemical synthesis
Phenothiazines - chemistry
Proline - chemistry
Sulfhydryl Compounds - chemistry
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Description
Summary:In the pro‐line of fire: A general and efficient cascade reaction approach to substituted phenothiazines, which relies on controlled sequential CuI/L‐proline‐catalyzed CS and CN bond formations, is described. DMSO=dimethylsulfoxide.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.200905646