Rhodium-catalyzed oxidative coupling of aromatic imines with internal alkynes via regioselective C-H bond cleavage

The rhodium-catalyzed oxidative coupling of aromatic imines with alkynes effectively proceeds via regioselective C-H bond cleavage to produce indenone imine and isoquinoline derivatives.

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Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2009-01 (34), p.5141-5143
Main Authors: Fukutani, Tatsuya, Umeda, Nobuyoshi, Hirano, Koji, Satoh, Tetsuya, Miura, Masahiro
Format: Article
Language:English
Subjects:
Alkynes - chemistry
Catalysis
Imines - chemical synthesis
Imines - chemistry
Indenes - chemical synthesis
Indenes - chemistry
Isoquinolines - chemical synthesis
Isoquinolines - chemistry
Molecular Structure
Oxidation-Reduction
Rhodium - chemistry
Stereoisomerism
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Description
Summary:The rhodium-catalyzed oxidative coupling of aromatic imines with alkynes effectively proceeds via regioselective C-H bond cleavage to produce indenone imine and isoquinoline derivatives.
ISSN:1359-7345
1364-548X
DOI:10.1039/b910198e