Encapsulation of cyclooctatetraenyl dianion in an unusual organic/inorganic lanthanide triple-decker sandwich complex

Treatment of [(COT)Nd(THF)(2)(mu-Cl)](2) with dilithium tetraphenyldisiloxanediolate, (LiOSiPh(2))(2)O, in a molar ratio of 1 : 4 afforded the novel organic/inorganic triple-decker complex (mu-eta(8):eta(8)-COT)[Nd{(Ph(2)SiO)(2)O}(2){Li(THF)(2)}{Li(THF)}](2) (1) which was structurally characterized...

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Bibliographic Details
Published in:Dalton transactions : an international journal of inorganic chemistry 2010-01, Vol.39 (29), p.6629-6631
Main Authors: Lorenz, Volker, Blaurock, Steffen, Hrib, Cristian G, Edelmann, Frank T
Format: Article
Language:English
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Summary:Treatment of [(COT)Nd(THF)(2)(mu-Cl)](2) with dilithium tetraphenyldisiloxanediolate, (LiOSiPh(2))(2)O, in a molar ratio of 1 : 4 afforded the novel organic/inorganic triple-decker complex (mu-eta(8):eta(8)-COT)[Nd{(Ph(2)SiO)(2)O}(2){Li(THF)(2)}{Li(THF)}](2) (1) which was structurally characterized by X-ray diffraction.
ISSN:1477-9226
1477-9234
DOI:10.1039/c0dt00094a