Reaction of Stable N‐Heterocyclic Silylenes and Germylenes with Muonium

Very a‐Mu‐sing! Reaction of a germylene with muonium (Mu) yields a germyl radical, in direct analogy to Mu attack at the ylideneic center of the corresponding N‐heterocyclic carbene. In contrast, the analogous silylene initially yields the expected silyl radical, but this radical rapidly attacks ano...

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Published in:Chemistry : a European journal 2009-08, Vol.15 (34), p.8409-8412
Main Authors: McCollum, Brett M., Brodovitch, Jean‐Claude, Clyburne, Jason A. C., Mitra, Amitabha, Percival, Paul W., Tomasik, Adam, West, Robert
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Language:English
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germanium
muonium
radical reactions
radicals
silicon
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cited_by cdi_FETCH-LOGICAL-c3441-fb99d7d44e9c49e3896e9c1419bc6d09415b9e53c6ae482d277570a050c3ba763
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creator McCollum, Brett M.
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description Very a‐Mu‐sing! Reaction of a germylene with muonium (Mu) yields a germyl radical, in direct analogy to Mu attack at the ylideneic center of the corresponding N‐heterocyclic carbene. In contrast, the analogous silylene initially yields the expected silyl radical, but this radical rapidly attacks another silylene molecule to generate a muoniated disilanyl radical.
doi_str_mv 10.1002/chem.200901281
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subjects germanium
muonium
radical reactions
radicals
silicon
title Reaction of Stable N‐Heterocyclic Silylenes and Germylenes with Muonium
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