Synthesis and Crystal Structure of NZP-Type Thorium−Zirconium Phosphate

Microcrystals of Th1/4Zr2(PO4)3 were synthesized by thermal treatment (900 °C) of the material obtained using sol−gel technology (including organic complex formation and etherification). Their structure [hexagonal, P3̅c, a = b = 8.7311(4) Å, c = 23.309(2) Å] includes the three-dimensional [Zr2(PO4)3...

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Bibliographic Details
Published in:Inorganic chemistry 2009-10, Vol.48 (19), p.9046-9047
Main Authors: Orlova, Albina I., Volgutov, Valeriy Yu, Castro, Germán R., García-Granda, Santiago, Khainakov, Sergei A., García, José R.
Format: Article
Language:English
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Summary:Microcrystals of Th1/4Zr2(PO4)3 were synthesized by thermal treatment (900 °C) of the material obtained using sol−gel technology (including organic complex formation and etherification). Their structure [hexagonal, P3̅c, a = b = 8.7311(4) Å, c = 23.309(2) Å] includes the three-dimensional [Zr2(PO4)3]− NASICON-type network and extraframework 6-fold-coordinated thorium(IV) cations.
ISSN:0020-1669
1520-510X
DOI:10.1021/ic9013812