Detection of ozone gas using gold nanoislands and surface plasmon resonance

• Published in: Talanta (Oxford) 2009-12, Vol.80 (2), p.777-780
• Main Authors: Pisarenko, Aleksey N., Spendel, Wolfgang U., Taylor, Richard T., Brown, Jordan D., Cox, James. A., Pacey, Gilbert E.
• Format: Article
• Language: English
• Subjects: Analytical chemistry; Chemistry; Exact sciences and technology; General, instrumentation; Gold - chemistry; Gold nanoislands; Metal Nanoparticles - chemistry; Metal Nanoparticles - ultrastructure; Microscopy, Atomic Force; Microscopy, Electron, Scanning; Ozone - analysis; Ozone - chemistry; Ozone detection; Reproducibility of Results; Spectrophotometry; Surface plasmon resonance; Surface Plasmon Resonance - methods
• ISSN: 0039-9140; 1873-3573
• DOI: 10.1016/j.talanta.2009.07.062

Gold nanoislands interact with gaseous ozone to produce a surface plasmon resonance shift, similarly to the interaction of ozone and gold nanoparticles in water. Gold nanoislands are produced by sputtering, which significantly simplifies the synthesis and produces controlled size for the gold nanoislands. The shift of surface plasmon resonance peak was monitored while gold nanoislands were exposed to variable concentration of gaseous ozone. The shift was then correlated with ozone concentration. Our current results indicate sensing gaseous ozone at concentration of as low as 20 μg/L is achievable. Gold nanoislands were reversed to their original wavelength and were able to cycle between the wavelengths as ozone was introduced and removed. Potentially, this system can be useful as a sensor that identifies the presence of ozone at low part-per-billion concentrations of ozone in gaseous media.