Adsorption and Catalytic Properties of the Inner Nanospace of a Gigantic Ring-Shaped Polyoxometalate Cluster

Functional inner space: A gigantic ring‐shaped {Mo154} polyoxometalate cluster anion can be stabilized by encapsulation in dimethyldioctadecylammonium (DODA) cations. Its inner nanospace enables adsorption of gases and vapors, and it acts as a water‐tolerant solid acid catalyst (see scheme).

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Bibliographic Details
Published in:Angewandte Chemie (International ed.) 2009-11, Vol.48 (46), p.8703-8706
Main Authors: Noro, Shin-ichiro, Tsunashima, Ryo, Kamiya, Yuichi, Uemura, Kazuhiro, Kita, Hidetoshi, Cronin, Leroy, Akutagawa, Tomoyuki, Nakamura, Takayoshi
Format: Article
Language:English
Subjects:
adsorption
heterogeneous catalysis
microporous materials
organic-inorganic hybrid composites
polyoxometalates
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Summary:Functional inner space: A gigantic ring‐shaped {Mo154} polyoxometalate cluster anion can be stabilized by encapsulation in dimethyldioctadecylammonium (DODA) cations. Its inner nanospace enables adsorption of gases and vapors, and it acts as a water‐tolerant solid acid catalyst (see scheme).
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.200903142