Synthesis of Interlocked 56-Membered Rings by Dynamic Self-Templating

A love of self: Narcissistic macrocyclic rings self‐assemble into highly ordered, chiral [2]‐catenanes displaying high component diastereoselectivity. The picture shows one such structure. One ring is shown in a space‐filling representation (C green, O red, N blue, H gray), while the other is shown...

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Bibliographic Details
Published in:Angewandte Chemie (International ed.) 2009-11, Vol.48 (46), p.8683-8686
Main Authors: Chung, Mee-Kyung, White, Peter S, Lee, Stephen J, Gagné, Michel R
Format: Article
Language:English
Subjects:
molecular recognition
self-assembly
supramolecular chemistry
template synthesis
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Summary:A love of self: Narcissistic macrocyclic rings self‐assemble into highly ordered, chiral [2]‐catenanes displaying high component diastereoselectivity. The picture shows one such structure. One ring is shown in a space‐filling representation (C green, O red, N blue, H gray), while the other is shown as orange sticks.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.200903478