Chemoselective Building Blocks for Dendrimers from Relative Reactivity Data

Competition reactions for the substitution of monochlorotriazines with different amines provide relative reactivity data that can be used to identify new groups for the chemoselective syntheses of dendrimers based on melamine. Target 1 is prepared using a one-pot per generation strategy without prot...

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Bibliographic Details
Published in:Organic letters 2003-06, Vol.5 (13), p.2359-2361
Main Authors: Steffensen, Mackay B, Simanek, Eric E
Format: Article
Language:English
Subjects:
Amines - chemistry
Databases, Factual
Hydrocarbons, Chlorinated - chemistry
Polymers - chemistry
Resins, Synthetic
Triazines - chemistry
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Summary:Competition reactions for the substitution of monochlorotriazines with different amines provide relative reactivity data that can be used to identify new groups for the chemoselective syntheses of dendrimers based on melamine. Target 1 is prepared using a one-pot per generation strategy without protecting group manipulations or functional group interconversions.
ISSN:1523-7060
1523-7052
DOI:10.1021/ol0347491