First Heterotrimetallic {3 d-4 d-4 f} Single Chain Magnet, Constructed from Anisotropic High-Spin Heterometallic Nodes and Paramagnetic Spacers

Three in one: Heterotrimetallic 1D coordination polymers are designed by assembling heteronuclear nodes (see figure), {Cu2Ln}, with paramagnetic octacyanido‐metallates, [M(CN)8]3− (M=Mo, W), acting as spacers. By choosing a strongly anisotropic lanthanide (DyIII), a new single chain magnet is obtain...

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Published in:Chemistry : a European journal 2009-11, Vol.15 (44), p.11808-11814
Main Authors: Visinescu, Diana, Madalan, Augustin M., Andruh, Marius, Duhayon, Carine, Sutter, Jean-Pascal, Ungur, Liviu, Van den Heuvel, Willem, Chibotaru, Liviu F.
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Language:English
Subjects:
copper
lanthanides
magnetic properties
molybdenum
single-chain magnets
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cited_by cdi_FETCH-LOGICAL-c4488-4ef85fa35883b52c548719b4f944081fad703f66a95c1d1fb791400e217d3ff23
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container_end_page 11814
container_issue 44
container_start_page 11808
container_title Chemistry : a European journal
container_volume 15
creator Visinescu, Diana
Madalan, Augustin M.
Andruh, Marius
Duhayon, Carine
Sutter, Jean-Pascal
Ungur, Liviu
Van den Heuvel, Willem
Chibotaru, Liviu F.
description Three in one: Heterotrimetallic 1D coordination polymers are designed by assembling heteronuclear nodes (see figure), {Cu2Ln}, with paramagnetic octacyanido‐metallates, [M(CN)8]3− (M=Mo, W), acting as spacers. By choosing a strongly anisotropic lanthanide (DyIII), a new single chain magnet is obtained.
doi_str_mv 10.1002/chem.200902408
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source Wiley-Blackwell Read & Publish Collection
subjects copper
lanthanides
magnetic properties
molybdenum
single-chain magnets
title First Heterotrimetallic {3 d-4 d-4 f} Single Chain Magnet, Constructed from Anisotropic High-Spin Heterometallic Nodes and Paramagnetic Spacers
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