Self-Assembly of a Pd6−Molecular Double-Square and a Cu3-Trigonalbipyramidal Cage via a New Tripodal Flexible Ligand

A new tripodal flexible ligand (L) containing pyrazolyl functionality has been prepared and successfully used to obtain a pd6 (1) molecular double-square and a cu3 trigonalbipyramidal cage (2), where complex 1 represents the first example of a double-square obtained using a flexible tripodal ligand.

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Bibliographic Details
Published in:Inorganic chemistry 2009-12, Vol.48 (23), p.10880-10882
Main Authors: Bar, Arun Kumar, Chakrabarty, Rajesh, Mukherjee, Partha Sarathi
Format: Article
Language:English
Online Access:Get full text
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Description
Summary:A new tripodal flexible ligand (L) containing pyrazolyl functionality has been prepared and successfully used to obtain a pd6 (1) molecular double-square and a cu3 trigonalbipyramidal cage (2), where complex 1 represents the first example of a double-square obtained using a flexible tripodal ligand.
ISSN:0020-1669
1520-510X
DOI:10.1021/ic901633g