Ionic and Organometallic Reductions with N-Heterocyclic Carbene Boranes

Surgical reduction: N‐Heterocyclic carbene–borane complexes such as depicted are neutral, organic soluble analogues of borohydride anions with a weak hydridic character, compatible with organometallic catalysis. They are applicable for surgical reductions in complex, multifunctional molecules.

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Bibliographic Details
Published in:Chemistry : a European journal 2009-12, Vol.15 (47), p.12937-12940
Main Authors: Chu, Qianli, Makhlouf Brahmi, Malika, Solovyev, Andrey, Ueng, Shau-Hua, Curran, Dennis P., Malacria, Max, Fensterbank, Louis, Lacôte, Emmanuel
Format: Article
Language:English
Subjects:
aromatic substitution
boranes
N-heterocyclic carbenes
palladium
reduction
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Summary:Surgical reduction: N‐Heterocyclic carbene–borane complexes such as depicted are neutral, organic soluble analogues of borohydride anions with a weak hydridic character, compatible with organometallic catalysis. They are applicable for surgical reductions in complex, multifunctional molecules.
ISSN:0947-6539
1521-3765
DOI:10.1002/chem.200902450