Asymmetric Organocatalytic Relay Cascades: Catalyst-Controlled Stereoisomer Selection in the Synthesis of Functionalized Cyclohexanes

Passing the baton: A relay cascade process provides cyclohexanes in a direct, efficient, and stereoselective manner. The triple‐cascade reaction is efficient, affords high selectivities, and has a broad scope, and different diastereomers are readily accessible by judicious choice of organocatalysts....

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Bibliographic Details
Published in:Angewandte Chemie (International ed.) 2009-01, Vol.48 (52), p.9834-9838
Main Authors: Wang, Yao, Han, Rong-Gang, Zhao, Yong-Long, Yang, Shu, Xu, Peng-Fei, Dixon, Darren J
Format: Article
Language:English
Subjects:
cascade reactions
diastereomers
enantioselectivity
organocatalysis
relay catalysis
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Summary:Passing the baton: A relay cascade process provides cyclohexanes in a direct, efficient, and stereoselective manner. The triple‐cascade reaction is efficient, affords high selectivities, and has a broad scope, and different diastereomers are readily accessible by judicious choice of organocatalysts.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.200905014