Bis[1-(p-chlorophenyl)-5-isopropylbiguanide-κ2N2, N4]nickel(II) dichloride dimethylformamide solvate

The asymmetric unit of the title compound, [Ni(C(11)H(16)ClN(5))(2)]Cl(2).C(3)H(7)NO, contains one monomeric nickel(II) complex cation, two Cl(-) anions and one dimethylformamide solvent molecule. The Ni atom is coordinated to each of two 1-(p-chlorophenyl)-5-isopropylbiguanide (proguanil) ligands v...

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Bibliographic Details
Published in:Acta crystallographica. Section C, Crystal structure communications Crystal structure communications, 2003-08, Vol.59 (Pt 8), p.m331-m333
Main Authors: BENTEFRIT, F, LEMOINE, P, NGUYEN-HUY, D, MORGANT, G, VIOSSAT, B
Format: Article
Language:English
Subjects:
Antibiotics. Antiinfectious agents. Antiparasitic agents
Antiparasitic agents
Biological and medical sciences
Condensed matter: structure, mechanical and thermal properties
Exact sciences and technology
Inorganic compounds
Medical sciences
Metal complexes
Pharmacology. Drug treatments
Physics
Structure of solids and liquids
crystallography
Structure of specific crystalline solids
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Summary:The asymmetric unit of the title compound, [Ni(C(11)H(16)ClN(5))(2)]Cl(2).C(3)H(7)NO, contains one monomeric nickel(II) complex cation, two Cl(-) anions and one dimethylformamide solvent molecule. The Ni atom is coordinated to each of two 1-(p-chlorophenyl)-5-isopropylbiguanide (proguanil) ligands via two N atoms. The complex exhibits a square-planar coordination, with the Ni atom lying 0.021 (2) A out of the basal plane. The crystal packing is characterized by several hydrogen bonds.
ISSN:0108-2701
1600-5759
DOI:10.1107/S0108270103013519