Crystalline-State Reaction with Allosteric Effect in Spin-Crossover, Interpenetrated Networks with Magnetic and Optical Bistability

A net change: A fully reversible ligand substitution involving coordination/uncoordination of gaseous water and pyrimidine induces the repetitive allosteric transformation of three interpenetrated nets into a single three‐dimensional net. The transformation does not affect the crystallinity of the s...

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Bibliographic Details
Published in:Angewandte Chemie International Edition 2003-08, Vol.42 (32), p.3760-3763
Main Authors: Niel, Virginie, Thompson, Amber L., Muñoz, M. Carmen, Galet, Ana, Goeta, Andrés E., Real, José A.
Format: Article
Language:English
Subjects:
allosterism
cooperative effects
crystalline-state reactions
N ligands
spin crossover
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Summary:A net change: A fully reversible ligand substitution involving coordination/uncoordination of gaseous water and pyrimidine induces the repetitive allosteric transformation of three interpenetrated nets into a single three‐dimensional net. The transformation does not affect the crystallinity of the sample but alters significantly the spin‐crossover transition; the compound shows magnetic and chromatic bistability (see picture).
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.200351853