Synthesis and catalytic activity of a chiral periodic mesoporous organosilica (ChiMO)

A chiral vanadyl salen complex having two peripheral trimethoxysilyl groups has been used to obtain a chiral periodic mesoporous organosilica having MCM-41 periodicity and the two Si-CH2 groups anchored on the framework; this solid induces 30% enantioselectivity in the cyanosilylation of benzaldehyd...

Full description

Saved in:
Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2003-01 (15), p.1860-1861
Main Authors: Baleizão, Carlos, Gigante, Bárbara, Das, Debasish, Alvaro, Mercedes, Garcia, Hermenegildo, Corma, Avelino
Format: Article
Language:English
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:A chiral vanadyl salen complex having two peripheral trimethoxysilyl groups has been used to obtain a chiral periodic mesoporous organosilica having MCM-41 periodicity and the two Si-CH2 groups anchored on the framework; this solid induces 30% enantioselectivity in the cyanosilylation of benzaldehyde.
ISSN:1359-7345
1364-548X
DOI:10.1039/b304814d