Am(III) adsorption on oxides of aluminium and silicon: effects of humic substances, pH, and ionic strength

• Published in: Journal of colloid and interface science 2003-09, Vol.265 (2), p.221-226
• Main Authors: Tao, Zuyi, Li, Weijuan, Zhang, Fuming, Ding, Youqian, Yu, Zhen
• Format: Article
• Language: English
• Subjects: Chemistry; Exact sciences and technology; General and physical chemistry; Solid-liquid interface; Surface physical chemistry
• ISSN: 0021-9797; 1095-7103
• DOI: 10.1016/S0021-9797(02)00156-X

The adsorption of Am(III) (total concentration 10 −9 mol/l) on alumina, silica, and hematite was studied by a batch technique. The effects of pH, ionic strength, and humic substances on the adsorption of Am(III) on alumina and silica were investigated, and the adsorption isotherms of Am(III) on alumina and silica at different pH values were determined. It was found that compared with the adsorption of Am(III) on alumina, the adsorbability of silica on the basis of mass is less, the relative adsorption rate on silica is slower, the sensitivity of adsorption on silica to ionic strength is less, the dependence of adsorption on silica on pH is gentler, and consequently that the adsorption characteristics of Am(III) on alumina and silica are distinctly different. The negative effect of fulvic acid on the adsorption on silica and the positive effect of humic acid on the adsorption on alumina were found. In contrast to the Am(III) adsorption on alumina and silica, a tremendously high adsorbability of Am(III) on hematite was found. The sequence of adsorbabilities of Am(III) on the basis of mass is Fe 2O 3 > Al 2O 3 > SiO 2.