Single-Wall Carbon Nanotube-Ferrocene Nanohybrids: Observing Intramolecular Electron Transfer in Functionalized SWNTs

A long‐lived charge‐separated state, SWNT.−–Fc.+, is formed by photoinduced electron transfer in a novel single‐wall carbon nanotube–ferrocene (SWNT–Fc) nanohybrid. The presence of SWNT.−, detected by laser flash photolysis, was confirmed by time‐resolved pulse radiolysis and steady‐state bulk elect...

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Bibliographic Details
Published in:Angewandte Chemie International Edition 2003-09, Vol.42 (35), p.4206-4209
Main Authors: Guldi, Dirk M., Marcaccio, Massimo, Paolucci, Demis, Paolucci, Francesco, Tagmatarchis, Nikos, Tasis, Dimitrios, Vázquez, Ester, Prato, Maurizio
Format: Article
Language:English
Subjects:
carbon
electron transfer
fluorescence
nanotechnology
nanotubes
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Summary:A long‐lived charge‐separated state, SWNT.−–Fc.+, is formed by photoinduced electron transfer in a novel single‐wall carbon nanotube–ferrocene (SWNT–Fc) nanohybrid. The presence of SWNT.−, detected by laser flash photolysis, was confirmed by time‐resolved pulse radiolysis and steady‐state bulk electrolysis.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.200351289