Metals Supported Water Monomers： the Bonding Nature Revisited

A single water monomer is known as a hard-to-observe molecule even in the presence of metal surfaces as supporting matrix. This review highlights effort in experimental characterizations and theoretical modeling of transition metals supported water monomers with attention given to its structure and...

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Published in:Journal of materials science & technology 2010-02, Vol.26 (2), p.97-105
Main Authors: Li, Jibiao, Zhu, Shenglong, Wang, Fuhui
Format: Article
Language:English
Subjects:
Adsorption
Surface bonding
Transition metals
Water monomer
差异分析
理论建模
相互作用力
粘结性
过渡金属
金属表面
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description A single water monomer is known as a hard-to-observe molecule even in the presence of metal surfaces as supporting matrix. This review highlights effort in experimental characterizations and theoretical modeling of transition metals supported water monomers with attention given to its structure and bonding, together with the insights that we have provided into the bonding nature of the water-interactions by the newly employed projected PDOS （partial density of states） difference analysis, which is proved to be an effective tool to be elucidate such bonding nature. The general s-d hybridization and d-shell effect are summarized, and how these effects can be tuned by tailoring local surface configurations is discussed.
doi_str_mv 10.1016/S1005-0302(10)60016-3
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1941-1162
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subjects Adsorption
Surface bonding
Transition metals
Water monomer
差异分析
理论建模
相互作用力
粘结性
过渡金属
金属表面
title Metals Supported Water Monomers： the Bonding Nature Revisited
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