Copolymerization of N,N-diallyl-N,N-dimethylammonium chloride and vinyl acetate

The free-radical copolymerization of N , N -diallyl- N , N -dimethylammonium chloride with vinyl acetate in DMSO, methanol, and a methanol-water (70: 30, mol %) mixture proceeds to yield statistical copolymers. The nature of solvents significantly affects the reactivity ratios of the comonomers. N ,...

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Bibliographic Details
Published in:Polymer science. Series B 2008-06, Vol.50 (5-6), p.139-143
Main Authors: Vorob’eva, A. I., Sagitova, D. R., Aleev, I. R., Volodina, V. P., Prochukhan, Yu. A., Monakov, Yu. B.
Format: Article
Language:English
Subjects:
Chemistry
Chemistry and Materials Science
Polymer Sciences
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Summary:The free-radical copolymerization of N , N -diallyl- N , N -dimethylammonium chloride with vinyl acetate in DMSO, methanol, and a methanol-water (70: 30, mol %) mixture proceeds to yield statistical copolymers. The nature of solvents significantly affects the reactivity ratios of the comonomers. N , N -Diallyl- N , N -dimethylammonium chloride shows a higher reactivity than vinyl acetate. The kinetic features of the processes have been investigated, and the structure and properties of the copolymers have been studied.
ISSN:1560-0904
1555-6123
DOI:10.1134/S1560090408050084