Recent Progress in Exploring Magnetocaloric Materials

• Published in: Advanced materials (Weinheim) 2009-12, Vol.21 (45), p.4545-4564
• Main Authors: Shen, B. G., Sun, J. R., Hu, F. X., Zhang, H. W., Cheng, Z. H.
• Format: Article
• Language: English
• Subjects: Alloys; Magnetic hysteresis; Magnetic properties; Magnetocaloric effect; Thermal hysteresis
• ISSN: 0935-9648; 1521-4095
• DOI: 10.1002/adma.200901072

The magnetic refrigeration technique based on the magnetocaloric effect (MCE) has attracted increasing interest because of its high efficiency and environment friendliness. In this article, our recent progress in exploring effective MCE materials is reviewed with emphasis on the MCE in the LaFe13−xSixbased alloys discovered by us. These alloys show large entropy changes over a wide temperature range near room temperature. The effects of magnetic rare‐earth doping, interstitial atoms and high pressure on the MCE have been systematically studied. Special issues, such as appropriate approaches to determining the MCE associated with the first‐order magnetic transition, the depression of magnetic and thermal hysteresis, and the key factors determining the magnetic exchange in alloys of this kind, are discussed. The applicability of giant MCE materials to magnetic refrigeration near ambient temperature is evaluated. A brief review of other materials with significant MCE is also presented. Recent progress in the study of the magnetic properties and magnetocaloric effects (MCEs) of the LaFe13−xSix‐based compounds, which have large MCEs over a wide temperature range near room temperature, is reviewed. The effects of magnetic rare‐earth doping, interstitial atoms and high pressure on the magnetic exchange, entropy change, and magnetic hysteresis are discussed. The applicability of the giant MCE materials to the magnetic refrigeration near ambient temperature is evaluated.