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Combustion kinetics of some spent oil shales from the Nagoorin deposit

The Nagoorin oil shale deposit comprises several units with a wide range of organic compositions that, on pyrolysis, yield spent shales with organic carbon concentrations of up to 50 wt %. The combustion kinetics of five units of the deposit were examined at temperatures up to 900 °C using a fluidiz...

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Bibliographic Details
Published in:Fuel (Guildford) 1988, Vol.67 (10), p.1365-1368
Main Author: Charlton, Brian G.
Format: Article
Language:English
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Summary:The Nagoorin oil shale deposit comprises several units with a wide range of organic compositions that, on pyrolysis, yield spent shales with organic carbon concentrations of up to 50 wt %. The combustion kinetics of five units of the deposit were examined at temperatures up to 900 °C using a fluidized bed batch technique and continuous analysis of the flue gases to determine the progress of the reaction. The five units show a range of shrinking-core reaction mechanisms — from ash diffusion control for the spent shales with the lowest carbon concentrations, to reaction control for the highest carbon concentration.
ISSN:0016-2361
1873-7153
DOI:10.1016/0016-2361(88)90121-4