Experimental investigation on regulated and unregulated emissions of a diesel/methanol compound combustion engine with and without diesel oxidation catalyst

• Published in: The Science of the total environment 2010-01, Vol.408 (4), p.865-872
• Main Authors: Zhang, Z.H., Cheung, C.S., Chan, T.L., Yao, C.D.
• Format: Article
• Language: English
• Subjects: Air Pollutants - analysis; Applied sciences; Atmospheric pollution; Catalysis; Diesel engine; Environmental Monitoring; Exact sciences and technology; Gasoline - analysis; Methanol; Oxidation-Reduction; Particulate emission; Particulate Matter - analysis; Pollution; Prevention and purification methods; Transports and other; Unregulated emissions; Vehicle Emissions - analysis; Vehicle Emissions - legislation & jurisprudence; Waste Products - analysis
• ISSN: 0048-9697; 1879-1026
• DOI: 10.1016/j.scitotenv.2009.10.060

The use of methanol in combination with diesel fuel is an effective measure to reduce particulate matter (PM) and nitrogen oxides (NOx) emissions from in-use diesel vehicles. In this study, a diesel/methanol compound combustion (DMCC) scheme was proposed and a 4-cylinder naturally-aspirated direct-injection diesel engine modified to operate on the proposed combustion scheme. The effect of DMCC and diesel oxidation catalyst (DOC) on the regulated emissions of total hydrocarbons (THC), carbon monoxide (CO), NOx and PM was investigated based on the Japanese 13 Mode test cycle. Certain unregulated emissions, including methane, ethyne, ethene, 1,3-butadiene, BTX (benzene, toluene, xylene), unburned methanol and formaldehyde were also evaluated based on the same test cycle. In addition, the soluble organic fraction (SOF) in the particulate and the particulate number concentration and size distribution were investigated at certain selected modes of operation. The results show that the DMCC scheme can effectively reduce NOx, particulate mass and number concentrations, ethyne, ethene and 1,3-butadiene emissions but significantly increase the emissions of THC, CO, NO 2, BTX, unburned methanol, formaldehyde, and the proportion of SOF in the particles. After the DOC, the emission of THC, CO, NO 2, as well as the unregulated gaseous emissions, can be significantly reduced when the exhaust gas temperature is sufficiently high while the particulate mass concentration is further reduced due to oxidation of the SOF.