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A comparative study on the kinetics and mechanisms of removal of Reactive Black 5 by adsorption onto activated carbons and bone char
The adsorption of a large reactive dye, Reactive Black 5, onto four adsorbents has been studied. A commercial active carbon, F400, was selected as a standard and two active carbons prepared from bamboo, a biomaterial. The two bamboo derived carbons, BACX2 and BACX6 had high specific surface areas, n...
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Published in: | Chemical engineering journal (Lausanne, Switzerland : 1996) Switzerland : 1996), 2010-03, Vol.157 (2), p.434-442 |
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container_title | Chemical engineering journal (Lausanne, Switzerland : 1996) |
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creator | Ip, Alvin W.M. Barford, John P. McKay, Gordon |
description | The adsorption of a large reactive dye, Reactive Black 5, onto four adsorbents has been studied. A commercial active carbon, F400, was selected as a standard and two active carbons prepared from bamboo, a biomaterial. The two bamboo derived carbons, BACX2 and BACX6 had high specific surface areas, namely, 2123 and 1400
m
2/g, respectively. A fourth widely used adsorbent, bone char, was also tested. The adsorption capacities for F400, bone char, BACX2 and BACX6 were 198, 160, 286 and 473
mg/g, respectively. A series of batch kinetics were carried out to investigate the rate and possible mechanism of Reactive Black 5 adsorption. Two pseudo-kinetic models and one intraparticle diffusion model were tested. The experimental concentration versus time decay curves were best explained by the intraparticle diffusion model. |
doi_str_mv | 10.1016/j.cej.2009.12.003 |
format | article |
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m
2/g, respectively. A fourth widely used adsorbent, bone char, was also tested. The adsorption capacities for F400, bone char, BACX2 and BACX6 were 198, 160, 286 and 473
mg/g, respectively. A series of batch kinetics were carried out to investigate the rate and possible mechanism of Reactive Black 5 adsorption. Two pseudo-kinetic models and one intraparticle diffusion model were tested. The experimental concentration versus time decay curves were best explained by the intraparticle diffusion model.</description><identifier>ISSN: 1385-8947</identifier><identifier>EISSN: 1873-3212</identifier><identifier>DOI: 10.1016/j.cej.2009.12.003</identifier><language>eng</language><publisher>Oxford: Elsevier B.V</publisher><subject>Adsorption ; Applied sciences ; Bamboo activated carbon ; Bone char ; Chemical engineering ; Exact sciences and technology ; Intraparticle diffusion ; Kinetics ; Reactive Black 5</subject><ispartof>Chemical engineering journal (Lausanne, Switzerland : 1996), 2010-03, Vol.157 (2), p.434-442</ispartof><rights>2009 Elsevier B.V.</rights><rights>2015 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c359t-f4f7a7964424d8a7001997a622a1a2630f187485cdfa0897fff6840ed4a7a93e3</citedby></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27922,27923</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=23055689$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Ip, Alvin W.M.</creatorcontrib><creatorcontrib>Barford, John P.</creatorcontrib><creatorcontrib>McKay, Gordon</creatorcontrib><title>A comparative study on the kinetics and mechanisms of removal of Reactive Black 5 by adsorption onto activated carbons and bone char</title><title>Chemical engineering journal (Lausanne, Switzerland : 1996)</title><description>The adsorption of a large reactive dye, Reactive Black 5, onto four adsorbents has been studied. A commercial active carbon, F400, was selected as a standard and two active carbons prepared from bamboo, a biomaterial. The two bamboo derived carbons, BACX2 and BACX6 had high specific surface areas, namely, 2123 and 1400
m
2/g, respectively. A fourth widely used adsorbent, bone char, was also tested. The adsorption capacities for F400, bone char, BACX2 and BACX6 were 198, 160, 286 and 473
mg/g, respectively. A series of batch kinetics were carried out to investigate the rate and possible mechanism of Reactive Black 5 adsorption. Two pseudo-kinetic models and one intraparticle diffusion model were tested. The experimental concentration versus time decay curves were best explained by the intraparticle diffusion model.</description><subject>Adsorption</subject><subject>Applied sciences</subject><subject>Bamboo activated carbon</subject><subject>Bone char</subject><subject>Chemical engineering</subject><subject>Exact sciences and technology</subject><subject>Intraparticle diffusion</subject><subject>Kinetics</subject><subject>Reactive Black 5</subject><issn>1385-8947</issn><issn>1873-3212</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2010</creationdate><recordtype>article</recordtype><recordid>eNp9kDtrHDEUhYeQQBwnPyCdmpBqJnrNSCKVY5wHGALGrsW1dIW1nhltJO3C9v7h0XpNylQ6xXc-cU_XfWR0YJRNXzaDw83AKTUD4wOl4lV3xrQSveCMv25Z6LHXRqq33btSNpTSyTBz1j1dEJeWLWSocY-k1J0_kLSS-oDkMa5YoysEVk8WdA-wxrIUkgLJuKQ9zMd4g-Ceu99mcI9kJPcHAr6kvK2xidJaE3kmoKInDvJ9Wk_KFpA0a37fvQkwF_zw8p53d9-vbi9_9te_f_y6vLjunRhN7YMMCpSZpOTSa1CUMmMUTJwDAz4JGtrFUo_OB6DaqBDCpCVFL0GBESjOu88n7zanPzss1S6xOJxnWDHtilVyEowarhvJTqTLqZSMwW5zXCAfLKP2OLjd2Da4PQ5uGbdt8Nb59GKH4mAOGVYXy78iF3QcJ20a9_XEYTt1HzHb4iKuDn3M6Kr1Kf7nl7_J6pZw</recordid><startdate>20100301</startdate><enddate>20100301</enddate><creator>Ip, Alvin W.M.</creator><creator>Barford, John P.</creator><creator>McKay, Gordon</creator><general>Elsevier B.V</general><general>Elsevier</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7QP</scope></search><sort><creationdate>20100301</creationdate><title>A comparative study on the kinetics and mechanisms of removal of Reactive Black 5 by adsorption onto activated carbons and bone char</title><author>Ip, Alvin W.M. ; Barford, John P. ; McKay, Gordon</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c359t-f4f7a7964424d8a7001997a622a1a2630f187485cdfa0897fff6840ed4a7a93e3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2010</creationdate><topic>Adsorption</topic><topic>Applied sciences</topic><topic>Bamboo activated carbon</topic><topic>Bone char</topic><topic>Chemical engineering</topic><topic>Exact sciences and technology</topic><topic>Intraparticle diffusion</topic><topic>Kinetics</topic><topic>Reactive Black 5</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Ip, Alvin W.M.</creatorcontrib><creatorcontrib>Barford, John P.</creatorcontrib><creatorcontrib>McKay, Gordon</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Calcium & Calcified Tissue Abstracts</collection><jtitle>Chemical engineering journal (Lausanne, Switzerland : 1996)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Ip, Alvin W.M.</au><au>Barford, John P.</au><au>McKay, Gordon</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>A comparative study on the kinetics and mechanisms of removal of Reactive Black 5 by adsorption onto activated carbons and bone char</atitle><jtitle>Chemical engineering journal (Lausanne, Switzerland : 1996)</jtitle><date>2010-03-01</date><risdate>2010</risdate><volume>157</volume><issue>2</issue><spage>434</spage><epage>442</epage><pages>434-442</pages><issn>1385-8947</issn><eissn>1873-3212</eissn><abstract>The adsorption of a large reactive dye, Reactive Black 5, onto four adsorbents has been studied. A commercial active carbon, F400, was selected as a standard and two active carbons prepared from bamboo, a biomaterial. The two bamboo derived carbons, BACX2 and BACX6 had high specific surface areas, namely, 2123 and 1400
m
2/g, respectively. A fourth widely used adsorbent, bone char, was also tested. The adsorption capacities for F400, bone char, BACX2 and BACX6 were 198, 160, 286 and 473
mg/g, respectively. A series of batch kinetics were carried out to investigate the rate and possible mechanism of Reactive Black 5 adsorption. Two pseudo-kinetic models and one intraparticle diffusion model were tested. The experimental concentration versus time decay curves were best explained by the intraparticle diffusion model.</abstract><cop>Oxford</cop><pub>Elsevier B.V</pub><doi>10.1016/j.cej.2009.12.003</doi><tpages>9</tpages></addata></record> |
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subjects | Adsorption Applied sciences Bamboo activated carbon Bone char Chemical engineering Exact sciences and technology Intraparticle diffusion Kinetics Reactive Black 5 |
title | A comparative study on the kinetics and mechanisms of removal of Reactive Black 5 by adsorption onto activated carbons and bone char |
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