Alkaline Fission of some 2-Substituted Dimethyl-ethyl-sulphonium Iodides

IN a paper published under this title, Crane and Rydon 1 described the behaviour towards alkali of some sulphonium iodides of the general structure, . Among such compounds those in which R was Ph.CO.O— and Ph.O— were remarkably labile, consuming alkali in the cold and decomposing on warming with alk...

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Bibliographic Details
Published in:Nature (London) 1950-09, Vol.166 (4218), p.404-405
Main Authors: MAMALIS, P., RYDON, H. N.
Format: Article
Language:English
Subjects:
Alkalies
Humanities and Social Sciences
Iodides
Iodine
Iodine Isotopes
letter
multidisciplinary
Old Medline
Science
Science (multidisciplinary)
Sulfonium Compounds
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Summary:IN a paper published under this title, Crane and Rydon 1 described the behaviour towards alkali of some sulphonium iodides of the general structure, . Among such compounds those in which R was Ph.CO.O— and Ph.O— were remarkably labile, consuming alkali in the cold and decomposing on warming with alkali according to the equation: .
ISSN:0028-0836
1476-4687
DOI:10.1038/166404a0