Copper-Catalyzed Sequential Alkyl/Aryl or Vinyl Esterification of Dicarboxylic Acid Anhydrides with Alkoxysilanes

A copper(I)-catalyzed bis-esterification of cyclic anhydrides with aryl and vinyl alkoxysilanes is described, in which the alkoxy and aryl (or vinyl) esters of dicarboxylic acids were prepared in one pot with moderate to good yields. Notably, vinyl trimethoxysilanes also worked well with this proced...

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Bibliographic Details
Published in:Journal of organic chemistry 2010-08, Vol.75 (15), p.5379-5381
Main Authors: Luo, Fang, Pan, Changduo, Qian, Pengcheng, Cheng, Jiang
Format: Article
Language:English
Subjects:
Chemistry
Exact sciences and technology
Kinetics and mechanisms
Organic chemistry
Reactivity and mechanisms
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Summary:A copper(I)-catalyzed bis-esterification of cyclic anhydrides with aryl and vinyl alkoxysilanes is described, in which the alkoxy and aryl (or vinyl) esters of dicarboxylic acids were prepared in one pot with moderate to good yields. Notably, vinyl trimethoxysilanes also worked well with this procedure.
ISSN:0022-3263
1520-6904
DOI:10.1021/jo100926a