Clusters for alkyne-azide click reactions

The clusters Ti(6)O(4)(OPr)(8)(OOC(CH(2))(2)C[triple bond]CH)(8) and [Zr(6)O(4)(OH)(4)(OOC(CH(2))(3)C[triple bond]CH)(12)](2) with acetylenic carboxylate ligands were prepared and structurally characterized in solution and in the crystalline state. Model reactions showed that they are suitable candi...

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Bibliographic Details
Published in:Dalton transactions : an international journal of inorganic chemistry 2010-09, Vol.39 (33), p.7640-7644
Main Authors: Heinz, Philipp, Puchberger, Michael, Bendova, Maria, Baumann, Stefan O, Schubert, Ulrich
Format: Article
Language:English
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Summary:The clusters Ti(6)O(4)(OPr)(8)(OOC(CH(2))(2)C[triple bond]CH)(8) and [Zr(6)O(4)(OH)(4)(OOC(CH(2))(3)C[triple bond]CH)(12)](2) with acetylenic carboxylate ligands were prepared and structurally characterized in solution and in the crystalline state. Model reactions showed that they are suitable candidates for the formation of cluster-based inorganic-organic hybrid materials by alkyne-azide click reactions.
ISSN:1477-9226
1477-9234
DOI:10.1039/c0dt00618a