Cycloadditions and Cyclizations of Acetylenic, Allenic, and Conjugated Dienyl Sulfones

The use of unsaturated sulfones in forming chemical rings is discussed. Actetylenic, allenic, and conjugated dienyl sulfones show unique properties as compared to vinyl sulfones in such reactions.

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Bibliographic Details
Published in:Chemical reviews 2010-08, Vol.110 (8), p.4498-4553
Main Authors: Back, Thomas G, Clary, Kristen N, Gao, Detian
Format: Article
Language:English
Subjects:
Chemical compounds
Chemical reactions
Chemistry
Cycloaddition
Forming
Molecular structure
Sulfones
Unsaturated
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Description
Summary:The use of unsaturated sulfones in forming chemical rings is discussed. Actetylenic, allenic, and conjugated dienyl sulfones show unique properties as compared to vinyl sulfones in such reactions.
ISSN:0009-2665
1520-6890
DOI:10.1021/cr1000546