Synthesis and characterization of a coupled binuclear Cu(I)/Cu(III) complex

The synthesis through reaction of a C(alpha),C(ortho) dilithiated phosphazene with CuBr and structural characterization of the first example of a binuclear mixed valence [Cu(I)(N(2))/Cu(III)(C(4))] complex showing a metal-metal bond, as well as its applications in cyclopropanation and oxidation reac...

Full description

Saved in:
Bibliographic Details
Published in:Journal of the American Chemical Society 2010-08, Vol.132 (31), p.10665-10667
Main Authors: García-López, Jesús, Yañez-Rodríguez, Víctor, Roces, Laura, García-Granda, Santiago, Martínez, Ana, Guevara-García, Alfredo, Castro, German R, Jiménez-Villacorta, Félix, Iglesias, María J, López Ortiz, Fernando
Format: Article
Language:English
Subjects:
Aziridines - chemistry
Copper - chemistry
Crystallography, X-Ray
Models, Molecular
Molecular Conformation
Organometallic Compounds - chemical synthesis
Organometallic Compounds - chemistry
Stereoisomerism
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:The synthesis through reaction of a C(alpha),C(ortho) dilithiated phosphazene with CuBr and structural characterization of the first example of a binuclear mixed valence [Cu(I)(N(2))/Cu(III)(C(4))] complex showing a metal-metal bond, as well as its applications in cyclopropanation and oxidation reactions, are described.
ISSN:1520-5126
DOI:10.1021/ja1034667