An unusual reactivity of BBr(3): Accessing tetrahydroisoquinoline units from N-phenethylimides

Isoindoloisoquinalinone, pyrroloisoquinolinone and benzo[a]quinolizinone units are constructed via intramolecular cyclization of the methoxy substituted N-phenethylimides using BBr(3).

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Bibliographic Details
Published in:Organic & biomolecular chemistry 2010-09, Vol.8 (18), p.4056-4058
Main Authors: Selvakumar, Jayaraman, Makriyannis, Alexandros, Ramanathan, Chinnasamy Ramaraj
Format: Article
Language:English
Subjects:
Boranes - chemistry
Chlorides - chemistry
Crystallography, X-Ray
Cyclization
Magnetic Resonance Spectroscopy
Models, Molecular
Molecular Structure
Phthalimides - chemistry
Stereoisomerism
Tetrahydroisoquinolines - chemical synthesis
Tetrahydroisoquinolines - chemistry
Online Access:Get full text
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Description
Summary:Isoindoloisoquinalinone, pyrroloisoquinolinone and benzo[a]quinolizinone units are constructed via intramolecular cyclization of the methoxy substituted N-phenethylimides using BBr(3).
ISSN:1477-0539
DOI:10.1039/c0ob00269k