Loading…

Ozonolysis of Maleic Acid Aerosols: Effect upon Aerosol Hygroscopicity, Phase and Mass

The hygroscopicity and mass loss of aerosols initially composed of maleic acid have been investigated before and after reaction with ozone. The phase of the aerosol, solid or aqueous, during the reaction with ozone strongly affects the composition of the processed aerosol. Furthermore the loss of ae...

Full description

Saved in:

Bibliographic Details
Published in:	Environmental science & technology 2010-09, Vol.44 (17), p.6656-6660
Main Authors:	Pope, F. D, Gallimore, P. J, Fuller, S. J, Cox, R. A, Kalberer, M
Format:	Article
Language:	English
Subjects:	Aerosols Aerosols - chemistry Analytical chemistry Applied sciences Aqueous chemistry Chemical bonds Chemical reactions Environmental Processes Exact sciences and technology Humidity Kinetics Maleates - chemistry Models, Chemical Molecular Weight Ozone - chemistry Pollution Reaction kinetics Time Factors Volatilization Wettability
Citations:	Items that this one cites Items that cite this one
Online Access:	Get full text
Tags:	Add Tag No Tags, Be the first to tag this record!

cited_by	cdi_FETCH-LOGICAL-a371t-1c654538813f3fb564e1c7ceeb7fc6188b9fe15b84ad3cdd470f95b1663101ba3
cites	cdi_FETCH-LOGICAL-a371t-1c654538813f3fb564e1c7ceeb7fc6188b9fe15b84ad3cdd470f95b1663101ba3
container_end_page	6660
container_issue	17
container_start_page	6656
container_title	Environmental science & technology
container_volume	44
creator	Pope, F. D Gallimore, P. J Fuller, S. J Cox, R. A Kalberer, M
description	The hygroscopicity and mass loss of aerosols initially composed of maleic acid have been investigated before and after reaction with ozone. The phase of the aerosol, solid or aqueous, during the reaction with ozone strongly affects the composition of the processed aerosol. Furthermore the loss of aerosol mass, via the production of volatile ozonolysis products, does not occur until the processed aerosol has existed as an aqueous phase aerosol. The loss rate of the aerosol mass appears to follow unimolecular first order kinetics which is consistent with the rate determining step being the cleavage of a weak hydroperoxide, or peroxide, bond (∼104 kJ mol−1). This speculative rate determining step, which is not based on chemical analysis, is possibly a universal feature in the ozonolysis of organic aerosol containing the alkene functionality.
doi_str_mv	10.1021/es1008278
format	article
fullrecord	<record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_749008410</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2142919501</sourcerecordid><originalsourceid>FETCH-LOGICAL-a371t-1c654538813f3fb564e1c7ceeb7fc6188b9fe15b84ad3cdd470f95b1663101ba3</originalsourceid><addsrcrecordid>eNpl0MFK7DAUBuAgis5VF76ABEHkgtVzmqZJ3Q2DVwVFFyruSpomWuk0Y890MT79jTgq6iohfPw552dsB-EIIcVjRwigU6VX2AhlConUElfZCABFUoj8YYP9IXoGgFSAXmcbKSjAVIkRu79-DV1oF9QQD55fmdY1lo9tU_Ox6wOFlk74qffOzvkwC93HKz9fPMaLDbPGNvPFIb95MuS46eqYQbTF1rxpyW0vz0129-_0dnKeXF6fXUzGl4kRCucJ2lxmUmiNwgtfyTxzaJV1rlLe5qh1VXiHstKZqYWt60yBL2SFeS4QsDJikx2858768DI4mpfThqxrW9O5MFCpsiI2kyFEufdDPoeh7-JwpZKocyVzHdHfd2TjbtQ7X876Zmr6RYlQvlVdflYd7e4ycKimrv6UH91GsL8EhqxpfW8629CXE1jIb85Y-hrq94f_AbQDkAE</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>751867568</pqid></control><display><type>article</type><title>Ozonolysis of Maleic Acid Aerosols: Effect upon Aerosol Hygroscopicity, Phase and Mass</title><source>American Chemical Society:Jisc Collections:American Chemical Society Read & Publish Agreement 2022-2024 (Reading list)</source><creator>Pope, F. D ; Gallimore, P. J ; Fuller, S. J ; Cox, R. A ; Kalberer, M</creator><creatorcontrib>Pope, F. D ; Gallimore, P. J ; Fuller, S. J ; Cox, R. A ; Kalberer, M</creatorcontrib><description>The hygroscopicity and mass loss of aerosols initially composed of maleic acid have been investigated before and after reaction with ozone. The phase of the aerosol, solid or aqueous, during the reaction with ozone strongly affects the composition of the processed aerosol. Furthermore the loss of aerosol mass, via the production of volatile ozonolysis products, does not occur until the processed aerosol has existed as an aqueous phase aerosol. The loss rate of the aerosol mass appears to follow unimolecular first order kinetics which is consistent with the rate determining step being the cleavage of a weak hydroperoxide, or peroxide, bond (∼104 kJ mol−1). This speculative rate determining step, which is not based on chemical analysis, is possibly a universal feature in the ozonolysis of organic aerosol containing the alkene functionality.</description><identifier>ISSN: 0013-936X</identifier><identifier>EISSN: 1520-5851</identifier><identifier>DOI: 10.1021/es1008278</identifier><identifier>PMID: 20701273</identifier><identifier>CODEN: ESTHAG</identifier><language>eng</language><publisher>Washington, DC: American Chemical Society</publisher><subject>Aerosols ; Aerosols - chemistry ; Analytical chemistry ; Applied sciences ; Aqueous chemistry ; Chemical bonds ; Chemical reactions ; Environmental Processes ; Exact sciences and technology ; Humidity ; Kinetics ; Maleates - chemistry ; Models, Chemical ; Molecular Weight ; Ozone - chemistry ; Pollution ; Reaction kinetics ; Time Factors ; Volatilization ; Wettability</subject><ispartof>Environmental science & technology, 2010-09, Vol.44 (17), p.6656-6660</ispartof><rights>Copyright © 2010 American Chemical Society</rights><rights>2015 INIST-CNRS</rights><rights>Copyright American Chemical Society Sep 1, 2010</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-a371t-1c654538813f3fb564e1c7ceeb7fc6188b9fe15b84ad3cdd470f95b1663101ba3</citedby><cites>FETCH-LOGICAL-a371t-1c654538813f3fb564e1c7ceeb7fc6188b9fe15b84ad3cdd470f95b1663101ba3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27923,27924</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=23195273$$DView record in Pascal Francis$$Hfree_for_read</backlink><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/20701273$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Pope, F. D</creatorcontrib><creatorcontrib>Gallimore, P. J</creatorcontrib><creatorcontrib>Fuller, S. J</creatorcontrib><creatorcontrib>Cox, R. A</creatorcontrib><creatorcontrib>Kalberer, M</creatorcontrib><title>Ozonolysis of Maleic Acid Aerosols: Effect upon Aerosol Hygroscopicity, Phase and Mass</title><title>Environmental science & technology</title><addtitle>Environ. Sci. Technol</addtitle><description>The hygroscopicity and mass loss of aerosols initially composed of maleic acid have been investigated before and after reaction with ozone. The phase of the aerosol, solid or aqueous, during the reaction with ozone strongly affects the composition of the processed aerosol. Furthermore the loss of aerosol mass, via the production of volatile ozonolysis products, does not occur until the processed aerosol has existed as an aqueous phase aerosol. The loss rate of the aerosol mass appears to follow unimolecular first order kinetics which is consistent with the rate determining step being the cleavage of a weak hydroperoxide, or peroxide, bond (∼104 kJ mol−1). This speculative rate determining step, which is not based on chemical analysis, is possibly a universal feature in the ozonolysis of organic aerosol containing the alkene functionality.</description><subject>Aerosols</subject><subject>Aerosols - chemistry</subject><subject>Analytical chemistry</subject><subject>Applied sciences</subject><subject>Aqueous chemistry</subject><subject>Chemical bonds</subject><subject>Chemical reactions</subject><subject>Environmental Processes</subject><subject>Exact sciences and technology</subject><subject>Humidity</subject><subject>Kinetics</subject><subject>Maleates - chemistry</subject><subject>Models, Chemical</subject><subject>Molecular Weight</subject><subject>Ozone - chemistry</subject><subject>Pollution</subject><subject>Reaction kinetics</subject><subject>Time Factors</subject><subject>Volatilization</subject><subject>Wettability</subject><issn>0013-936X</issn><issn>1520-5851</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2010</creationdate><recordtype>article</recordtype><recordid>eNpl0MFK7DAUBuAgis5VF76ABEHkgtVzmqZJ3Q2DVwVFFyruSpomWuk0Y890MT79jTgq6iohfPw552dsB-EIIcVjRwigU6VX2AhlConUElfZCABFUoj8YYP9IXoGgFSAXmcbKSjAVIkRu79-DV1oF9QQD55fmdY1lo9tU_Ox6wOFlk74qffOzvkwC93HKz9fPMaLDbPGNvPFIb95MuS46eqYQbTF1rxpyW0vz0129-_0dnKeXF6fXUzGl4kRCucJ2lxmUmiNwgtfyTxzaJV1rlLe5qh1VXiHstKZqYWt60yBL2SFeS4QsDJikx2858768DI4mpfThqxrW9O5MFCpsiI2kyFEufdDPoeh7-JwpZKocyVzHdHfd2TjbtQ7X876Zmr6RYlQvlVdflYd7e4ycKimrv6UH91GsL8EhqxpfW8629CXE1jIb85Y-hrq94f_AbQDkAE</recordid><startdate>20100901</startdate><enddate>20100901</enddate><creator>Pope, F. D</creator><creator>Gallimore, P. J</creator><creator>Fuller, S. J</creator><creator>Cox, R. A</creator><creator>Kalberer, M</creator><general>American Chemical Society</general><scope>IQODW</scope><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7QO</scope><scope>7ST</scope><scope>7T7</scope><scope>7U7</scope><scope>8FD</scope><scope>C1K</scope><scope>FR3</scope><scope>P64</scope><scope>SOI</scope><scope>7X8</scope></search><sort><creationdate>20100901</creationdate><title>Ozonolysis of Maleic Acid Aerosols: Effect upon Aerosol Hygroscopicity, Phase and Mass</title><author>Pope, F. D ; Gallimore, P. J ; Fuller, S. J ; Cox, R. A ; Kalberer, M</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a371t-1c654538813f3fb564e1c7ceeb7fc6188b9fe15b84ad3cdd470f95b1663101ba3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2010</creationdate><topic>Aerosols</topic><topic>Aerosols - chemistry</topic><topic>Analytical chemistry</topic><topic>Applied sciences</topic><topic>Aqueous chemistry</topic><topic>Chemical bonds</topic><topic>Chemical reactions</topic><topic>Environmental Processes</topic><topic>Exact sciences and technology</topic><topic>Humidity</topic><topic>Kinetics</topic><topic>Maleates - chemistry</topic><topic>Models, Chemical</topic><topic>Molecular Weight</topic><topic>Ozone - chemistry</topic><topic>Pollution</topic><topic>Reaction kinetics</topic><topic>Time Factors</topic><topic>Volatilization</topic><topic>Wettability</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Pope, F. D</creatorcontrib><creatorcontrib>Gallimore, P. J</creatorcontrib><creatorcontrib>Fuller, S. J</creatorcontrib><creatorcontrib>Cox, R. A</creatorcontrib><creatorcontrib>Kalberer, M</creatorcontrib><collection>Pascal-Francis</collection><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>Biotechnology Research Abstracts</collection><collection>Environment Abstracts</collection><collection>Industrial and Applied Microbiology Abstracts (Microbiology A)</collection><collection>Toxicology Abstracts</collection><collection>Technology Research Database</collection><collection>Environmental Sciences and Pollution Management</collection><collection>Engineering Research Database</collection><collection>Biotechnology and BioEngineering Abstracts</collection><collection>Environment Abstracts</collection><collection>MEDLINE - Academic</collection><jtitle>Environmental science & technology</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Pope, F. D</au><au>Gallimore, P. J</au><au>Fuller, S. J</au><au>Cox, R. A</au><au>Kalberer, M</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Ozonolysis of Maleic Acid Aerosols: Effect upon Aerosol Hygroscopicity, Phase and Mass</atitle><jtitle>Environmental science & technology</jtitle><addtitle>Environ. Sci. Technol</addtitle><date>2010-09-01</date><risdate>2010</risdate><volume>44</volume><issue>17</issue><spage>6656</spage><epage>6660</epage><pages>6656-6660</pages><issn>0013-936X</issn><eissn>1520-5851</eissn><coden>ESTHAG</coden><abstract>The hygroscopicity and mass loss of aerosols initially composed of maleic acid have been investigated before and after reaction with ozone. The phase of the aerosol, solid or aqueous, during the reaction with ozone strongly affects the composition of the processed aerosol. Furthermore the loss of aerosol mass, via the production of volatile ozonolysis products, does not occur until the processed aerosol has existed as an aqueous phase aerosol. The loss rate of the aerosol mass appears to follow unimolecular first order kinetics which is consistent with the rate determining step being the cleavage of a weak hydroperoxide, or peroxide, bond (∼104 kJ mol−1). This speculative rate determining step, which is not based on chemical analysis, is possibly a universal feature in the ozonolysis of organic aerosol containing the alkene functionality.</abstract><cop>Washington, DC</cop><pub>American Chemical Society</pub><pmid>20701273</pmid><doi>10.1021/es1008278</doi><tpages>5</tpages></addata></record>
fulltext	fulltext
identifier	ISSN: 0013-936X
ispartof	Environmental science & technology, 2010-09, Vol.44 (17), p.6656-6660
issn	0013-936X 1520-5851
language	eng
recordid	cdi_proquest_miscellaneous_749008410
source	American Chemical Society:Jisc Collections:American Chemical Society Read & Publish Agreement 2022-2024 (Reading list)
subjects	Aerosols Aerosols - chemistry Analytical chemistry Applied sciences Aqueous chemistry Chemical bonds Chemical reactions Environmental Processes Exact sciences and technology Humidity Kinetics Maleates - chemistry Models, Chemical Molecular Weight Ozone - chemistry Pollution Reaction kinetics Time Factors Volatilization Wettability
title	Ozonolysis of Maleic Acid Aerosols: Effect upon Aerosol Hygroscopicity, Phase and Mass
url	http://sfxeu10.hosted.exlibrisgroup.com/loughborough?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-08T19%3A14%3A40IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Ozonolysis%20of%20Maleic%20Acid%20Aerosols:%20Effect%20upon%20Aerosol%20Hygroscopicity,%20Phase%20and%20Mass&rft.jtitle=Environmental%20science%20&%20technology&rft.au=Pope,%20F.%20D&rft.date=2010-09-01&rft.volume=44&rft.issue=17&rft.spage=6656&rft.epage=6660&rft.pages=6656-6660&rft.issn=0013-936X&rft.eissn=1520-5851&rft.coden=ESTHAG&rft_id=info:doi/10.1021/es1008278&rft_dat=%3Cproquest_cross%3E2142919501%3C/proquest_cross%3E%3Cgrp_id%3Ecdi_FETCH-LOGICAL-a371t-1c654538813f3fb564e1c7ceeb7fc6188b9fe15b84ad3cdd470f95b1663101ba3%3C/grp_id%3E%3Coa%3E%3C/oa%3E%3Curl%3E%3C/url%3E&rft_id=info:oai/&rft_pqid=751867568&rft_id=info:pmid/20701273&rfr_iscdi=true