The influence of the method of butadiene rubbers cross-linking on their thermal properties

The paper presents results of thermal properties measurements of cis -1,4-polybutadienes with different contents of cis -1,4 mers before and after their conventional cross-linking with the use of dicumyl peroxide and non-conventional cross-linking by means of iodoform. The measurements were carried...

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Bibliographic Details
Published in:Journal of thermal analysis and calorimetry 2009-05, Vol.96 (2), p.561-565
Main Authors: Janowska, G., Kucharska, A.
Format: Article
Language:English
Subjects:
Analytical Chemistry
Applied sciences
Butadiene
Calorimetry
Chemical reactions
Chemistry
Chemistry and Materials Science
Crosslinking
Dicumyl peroxide
Differential scanning calorimetry
Exact sciences and technology
Inorganic Chemistry
Measurement Science and Instrumentation
Organic polymers
Physical Chemistry
Physicochemistry of polymers
Polymer Sciences
Properties and characterization
Thermal and thermodynamic properties
Thermal properties
Thermogravimetry
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Summary:The paper presents results of thermal properties measurements of cis -1,4-polybutadienes with different contents of cis -1,4 mers before and after their conventional cross-linking with the use of dicumyl peroxide and non-conventional cross-linking by means of iodoform. The measurements were carried out under the atmosphere of neutral gas using a micro-calorimeter, DSC and thermogravimetry, TG. The thermal curves have been interpreted from the point of view of phase transitions and chemical reactions of investigated elastomers.
ISSN:1388-6150
1588-2926
1572-8943
DOI:10.1007/s10973-008-9395-2