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Synergistic effect of Pd–Au bimetallic surfaces in Au-covered Pd nanowires studied for ethanol oxidation

Highly ordered PdAu nanowire arrays (NWAs) have been successfully prepared by the combination of anodized aluminum oxide (AAO) template-electrodeposition and Pd NWAs reacting with HAuCl 4. The synergistic effect of Pd–Au bimetallic surfaces in Au-covered Pd nanowires has been demonstrated by cyclic...

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Published in:Electrochimica acta 2010-02, Vol.55 (7), p.2295-2298
Main Authors: Cheng, Faliang, Dai, Xiangcheng, Wang, Hong, Jiang, San Ping, Zhang, Min, Xu, Changwei
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Language:English
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description Highly ordered PdAu nanowire arrays (NWAs) have been successfully prepared by the combination of anodized aluminum oxide (AAO) template-electrodeposition and Pd NWAs reacting with HAuCl 4. The synergistic effect of Pd–Au bimetallic surfaces in Au-covered Pd nanowires has been demonstrated by cyclic voltammogram (CV) because the onset potential ( E s) of ethanol oxidation on the PdAu NWAs electrode is 123 mV more negative compared with that on the Pd NWAs electrode. The PdAu NWAs shows higher activity and better poisoning-resistance behavior than the Pd NWAs for ethanol electrooxidation.
doi_str_mv 10.1016/j.electacta.2009.11.076
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subjects Aluminum oxide
Anodizing
Applied sciences
Bimetals
Chemistry
Electrochemistry
Electrodes
Electrodes: preparations and properties
Energy
Energy. Thermal use of fuels
Equipments for energy generation and conversion: thermal, electrical, mechanical energy, etc
Ethanol
Ethanol electrooxidation
Ethyl alcohol
Exact sciences and technology
Fuel cell
Fuel cells
General and physical chemistry
Nanowire arrays
Nanowires
Other electrodes
Palladium
Palladium–gold
Synergistic effect
title Synergistic effect of Pd–Au bimetallic surfaces in Au-covered Pd nanowires studied for ethanol oxidation
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