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Infrared and Raman spectroscopic investigations of xMnO (100− x)[As 2O 3 TeO 2] glass system

xMnO·(100− x)[As 2O 3·TeO 2] glass system, with 0≤ x≤50 mol %, was prepared and investigated by FT-IR and Raman spectroscopies in order to determine its structure and the changes induced by the increasing of MnO content. The results offered by FT-IR and Raman spectroscopies suggest a structure forme...

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Bibliographic Details
Published in:Physica. B, Condensed matter Condensed matter, 2010-05, Vol.405 (9), p.2259-2262
Main Authors: Ardelean, I., Lupsor, Simona, Rusu, Dorina
Format: Article
Language:English
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Summary:xMnO·(100− x)[As 2O 3·TeO 2] glass system, with 0≤ x≤50 mol %, was prepared and investigated by FT-IR and Raman spectroscopies in order to determine its structure and the changes induced by the increasing of MnO content. The results offered by FT-IR and Raman spectroscopies suggest a structure formed by AsO 3, TeO 4 tbp and TeO 3 tp units. The presence of MnO 2 units was confirmed by FT-IR spectra only for high concentration of MnO.
ISSN:0921-4526
1873-2135
DOI:10.1016/j.physb.2010.02.022