Characterization investigations of a mechanically alloyed and sintered Al–2 wt%Cu alloy reinforced with WC particles

• Published in: Journal of alloys and compounds 2010-04, Vol.496 (1), p.212-217
• Main Authors: Evirgen, Alper, Öveçoğlu, M. Lütfi
• Format: Article
• Language: English
• Subjects: Aluminum; Aluminum base alloys; Applied sciences; Carbides; Characterization; Density; Differential scanning calorimetry; Dispersion hardening metals; Exact sciences and technology; Intermetallics; Mechanical alloying; Metals. Metallurgy; Microhardness; Microstructure; Powder metallurgy. Composite materials; Production techniques; Scanning electron microscopy; Sintering; Technology; Tungsten carbide
• ISSN: 0925-8388; 1873-4669
• DOI: 10.1016/j.jallcom.2010.02.136

Elemental powders of Al, Cu and WC were mechanically alloyed in a high energy mill for milling durations of 1 h, 2 h, 3 h and 5 h to constitute the Al–2Cu–7WC (wt%) composition. The microstructural characterizations of powders were performed with SEM and XRD analyses and additionally microhardness tests were applied for mechanical characterization. DSC and post-XRD tests were carried out to study the phase transformations in powder form. The MA’d powder pellets were sintered under inert Ar atmosphere at 650 °C for 4 h. XRD, SEM, and EDS investigations and microhardness measurements were conducted for the microstructural and mechanical characterization of sintered samples. DSC and XRD examinations of powders MA’d for 5 h showed that decomposition of WC after 450 °C led to the formation of Al 12W intermetallic which provided high strength composites. The XRD and SEM investigations revealed the presence of Al 12W phase in all sintered samples. Microhardness of sintered samples increased with the increase of MA duration. A maximum Vickers hardness of 201 HV and a maximum sinter density of 93.3% have been observed for the sample MA’d for 5 h.