Optical Operation by Chromophores Featuring 4,5-Dicyanoimidazole Embedded within Poly(methyl methacrylate) Matrices

• Published in: The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory Molecules, spectroscopy, kinetics, environment, & general theory, 2010-09, Vol.114 (35), p.9440-9446
• Main Authors: Kulhánek, J, Bureš, F, Wojciechowski, A, Makowska-Janusik, M, Gondek, E, Kityk, I. V
• Format: Article
• Language: English
• Subjects: A: Kinetics, Spectroscopy; Imidazoles - chemistry; Molecular Dynamics Simulation; Molecular Structure; Optical Phenomena; Polymethyl Methacrylate - chemistry; Quantum Theory
• ISSN: 1089-5639; 1520-5215
• DOI: 10.1021/jp1047634

We have studied photoinduced absorption, birefringence, and optical second-harmonic generation in poly(methyl methacrylate) (PMMA) films doped by organic chromophores featuring 4,5-dicyanoimidazole in the weight content equal to 5%. The chromophores indicated as IM1−IM6 were synthesized from 2-bromo-1-methylimidazole-4,5-dicarbonitrile by either nucleophilic substitution or Suzuki−Miyaura cross-coupling reaction. The samples were obtained as films of several micrometers thickness by the spin-coating method on a quartz substrate. Measurements of the optically induced birefringence were done by the Senarmont method at wavelength 1150 nm, and photoinduced absorption was studied in the spectral range 250−700 nm under optical treatment by 300 mW cw 532 nm laser. Photoinduced optical effects were studied by bicolor 1064 and 532 nm coherent laser pulses. The maximal changes were observed for the ratio between fundamental and writing beam intensities equal to about 7:1. To interpret the observed experimental measurements, theoretical simulations of photoinduced optical properties were performed by quantum chemical computational methods.