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Unified Internal Architecture and Surface Barriers for Molecular Diffusion of Microporous Crystalline Aluminophosphates
Starless molecular sieves: The starlike appearence of confocal fluorescence microscopy (CFM) images of large crystals of the AlPO‐5 family of microporous materials is due to the presence of barriers to molecular diffusion in the internal crystal architecture (see picture) rather than a star‐shaped s...
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| Published in: | Angewandte Chemie (International ed.) 2010-09, Vol.49 (38), p.6790-6794 |
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| Main Authors: | , , , , , , , |
| Format: | Article |
| Language: | English |
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| cited_by | cdi_FETCH-LOGICAL-c4063-b966d5bfd4832d0479a03ad73405b80f54ad459c6a12031fe534c1bbc57300cb3 |
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| cites | cdi_FETCH-LOGICAL-c4063-b966d5bfd4832d0479a03ad73405b80f54ad459c6a12031fe534c1bbc57300cb3 |
| container_end_page | 6794 |
| container_issue | 38 |
| container_start_page | 6790 |
| container_title | Angewandte Chemie (International ed.) |
| container_volume | 49 |
| creator | Karwacki, Lukasz van der Bij, Hendrik E Kornatowski, Jan Cubillas, Pablo Drury, Martyn R de Winter, D.A. Matthijs Anderson, Michael W Weckhuysen, Bert M |
| description | Starless molecular sieves: The starlike appearence of confocal fluorescence microscopy (CFM) images of large crystals of the AlPO‐5 family of microporous materials is due to the presence of barriers to molecular diffusion in the internal crystal architecture (see picture) rather than a star‐shaped subcrystal according to studies by CFM, focused ion beam milling, electron backscatter diffraction, and atomic force microscopy. |
| doi_str_mv | 10.1002/anie.201003273 |
| format | article |
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| identifier | ISSN: 1433-7851 |
| ispartof | Angewandte Chemie (International ed.), 2010-09, Vol.49 (38), p.6790-6794 |
| issn | 1433-7851 1521-3773 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_754001821 |
| source | Wiley-Blackwell Read & Publish Collection |
| subjects | Aluminum Compounds - chemistry confocal microscopy crystal intergrowth Crystallization Diffusion microporous materials Microscopy, Atomic Force Microscopy, Confocal Phosphates - chemistry Porosity structure elucidation zeolites Zeolites - chemistry |
| title | Unified Internal Architecture and Surface Barriers for Molecular Diffusion of Microporous Crystalline Aluminophosphates |
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