Colloidal Stabilization of Nanoparticles in Concentrated Suspensions

• Published in: Langmuir 2007-01, Vol.23 (3), p.1081-1090
• Main Authors: Studart, André R, Amstad, Esther, Gauckler, Ludwig J
• Format: Article
• Language: English
• Subjects: Aluminum Oxide; Chemistry; Colloidal state and disperse state; Colloids; Electrochemistry; Exact sciences and technology; General and physical chemistry; Nanoparticles; Physical and chemical studies. Granulometry. Electrokinetic phenomena; Surface physical chemistry; Viscosity; Water
• ISSN: 0743-7463; 1520-5827
• DOI: 10.1021/la062042s

The stabilization of nanoparticles in concentrated aqueous suspensions is required in many manufacturing technologies and industrial products. Nanoparticles are commonly stabilized through the adsorption of a dispersant layer around the particle surface. The formation of a dispersant layer (adlayer) of appropriate thickness is crucial for the stabilization of suspensions containing high nanoparticle concentrations. Thick adlayers result in an excessive excluded volume around the particles, whereas thin adlayers lead to particle agglomeration. Both effects reduce the maximum concentration of nanoparticles in the suspension. However, conventional dispersants do not allow for a systematic control of the adlayer thickness on the particle surface. In this study, we synthesized dispersants with a molecular architecture that enables better control over the particle adlayer thickness. By tailoring the chemistry and length of these novel dispersants, we were able to prepare fluid suspensions (viscosity < 1 Pa·s at 100 s-1) with more than 40 vol % of 65-nm alumina particles in water, as opposed to the 30 vol % achieved with a state-of-the-art dispersing agent. This remarkably high concentration facilitates the fabrication of a wide range of products and intermediates in materials technology, cosmetics, pharmacy, and in all other areas where concentrated nanoparticle suspensions are required. On the basis of the proposed molecular architecture, one can also envisage other similar molecules that could be successfully applied for the functionalization of surfaces for biosensing, chromatography, medical imaging, drug delivery, and aqueous lubrication, among others.