Molybdenum-Mediated Carbonylation of Aryl Halides with Nucleophiles Using Microwave Irradiation

A new, efficient, and practical molybdenum-mediated carbonylation of aryl and heteroaryl halides with a variety of nucleophiles is described using microwave irradiation. A range of reactions illustrating the wide scope of this chemistry were carried out and proceeded in good to excellent yields.

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Bibliographic Details
Published in:Organic letters 2010-10, Vol.12 (19), p.4280-4283
Main Authors: Roberts, Bryan, Liptrot, David, Alcaraz, Lilian, Luker, Tim, Stocks, Michael J
Format: Article
Language:English
Subjects:
Carbonic Acid - chemistry
Halogens - chemistry
Microwaves
Molecular Structure
Molybdenum - chemistry
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Description
Summary:A new, efficient, and practical molybdenum-mediated carbonylation of aryl and heteroaryl halides with a variety of nucleophiles is described using microwave irradiation. A range of reactions illustrating the wide scope of this chemistry were carried out and proceeded in good to excellent yields.
ISSN:1523-7060
1523-7052
DOI:10.1021/ol1016965