Stereoselective cis-Addition of Aromatic C−H Bonds to Alkynes Catalyzed by Dinuclear Palladium Complexes

Reactions of alkynes with arenes proceeded in the presence of dinuclear palladium complexes and trialkylboranes to yield alkyne hydroarylation products with high stereoselectivity. In the reactions of monosubstituted benzenes, meta and para products were formed in statistical ratios, while no ortho...

Full description

Saved in:
Bibliographic Details
Published in:Journal of the American Chemical Society 2003-10, Vol.125 (40), p.12102-12103
Main Authors: Tsukada, Naofumi, Mitsuboshi, Tomohiro, Setoguchi, Hiroyuki, Inoue, Yoshio
Format: Article
Language:English
Subjects:
Chemical reactivity
Chemistry
Exact sciences and technology
Organic chemistry
Reactivity and mechanisms
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:Reactions of alkynes with arenes proceeded in the presence of dinuclear palladium complexes and trialkylboranes to yield alkyne hydroarylation products with high stereoselectivity. In the reactions of monosubstituted benzenes, meta and para products were formed in statistical ratios, while no ortho isomers were detected.
ISSN:0002-7863
1520-5126
DOI:10.1021/ja0375075