Intermolecular Palladium‐Catalyzed Diamination of Unactivated Alkenes

Adding 2Ns: Palladium catalysis introduces two nitrogen groups in a new regio and chemoselective diamination of non‐activated alkenes that proceeds under entirely intermolecular reaction control. This palladium‐catalyzed reaction employs commercial nitrogen sources in combination with a hypervalent...

Full description

Saved in:
Bibliographic Details
Published in:Angewandte Chemie (International ed.) 2010-10, Vol.49 (44), p.8109-8111
Main Authors: Iglesias, Álvaro, Pérez, Edwin G, Muñiz, Kilian
Format: Article
Language:English
Subjects:
alkenes
amides
diamines
oxidation
palladium
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:Adding 2Ns: Palladium catalysis introduces two nitrogen groups in a new regio and chemoselective diamination of non‐activated alkenes that proceeds under entirely intermolecular reaction control. This palladium‐catalyzed reaction employs commercial nitrogen sources in combination with a hypervalent iodo(III) reagent as oxidant (see scheme; Tos=toluenesulfonyl).
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.201003653