Effects of electric voltage and sodium chloride level on electrolysis of swine wastewater

• Published in: Journal of hazardous materials 2010-08, Vol.180 (1), p.535-541
• Main Authors: Cho, J.H., Lee, J.E., Ra, C.S.
• Format: Article
• Language: English
• Subjects: Animals; Anodes; Applied sciences; Chemical engineering; Color; Electric potential; Electricity; Electrolysis; Electrooxidation; Exact sciences and technology; General purification processes; Hypochlorite; Industrial Waste; Optimization; Pollutants; Pollution; Reactors; Sodium Chloride - analysis; Swine; Swine wastewater; Voltage; Waste water; Wastewaters; Water Pollutants; Water treatment and pollution
• ISSN: 0304-3894; 1873-3336
• DOI: 10.1016/j.jhazmat.2010.04.067

The effects of electric voltage and NaCl concentration on the removal of pollutants in swine wastewater were investigated to determine the optimum operation conditions for a designed electrolysis process. An up-flow electrolytic reactor was fabricated from Plexiglas, and one titanium anode coated with iridium oxide (IrO 2) and two stainless steel cathodes were installed in it. The anode surface area was 80 cm 2/L and the hydraulic retention time (HRT) was 6 h. The results indicated that the pollutant removal was highly proportional to the electric voltage and removal could be enhanced by adding NaCl. The removal efficiencies of NH 4-N, soluble nitrogen (NH 4-N plus NO x -N), soluble total organic carbon (STOC), and color were proportional to the NaCl level up to 0.05% NaCl level, beyond which no further enhancement in removal was observed. However, such a tendency was not observed in the case of PO 4-P removal. The obtained results indicate that 7 V and 0.05% (8.56 mM) NaCl level would be the optimum conditions for the designed electrolysis process. Under these conditions, the average removal efficiencies of NH 4-N, soluble nitrogen, PO 4-P, STOC, and color were 99%, 94%, 59%, 64%, and 93%, respectively.