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Characterization of iron oxide nanocatalyst in mineralization processes
The reuse of iron oxide nanoparticles as a catalyst of organic matter in the H 2O 2/iron oxide mineralization process was investigated. The particle size and morphology of iron oxide particles obtained from TEM (Transmission Electron Microscopy) images and DLS (Dynamic Light Scattering) measurements...
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Published in: | Desalination 2010-11, Vol.262 (1), p.15-20 |
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creator | Bach, Altai Zach-Maor, Adva Semiat, Raphael |
description | The reuse of iron oxide nanoparticles as a catalyst of organic matter in the H
2O
2/iron oxide mineralization process was investigated. The particle size and morphology of iron oxide particles obtained from TEM (Transmission Electron Microscopy) images and DLS (Dynamic Light Scattering) measurements, indicate the formation of a rod-like morphology with an average length of 50
±
10
nm. An electron diffraction pattern identified the particles as either α-FeOOH or β-FeOOH. Stability of iron oxide nanoparticles in organic model compound solutions was studied as a function of pH solution and was correlated with average size. The optimal pH for maximum mineralization in the H
2O
2/iron oxide system was found to be 2.8. Finally, results indicated that at least seven stages of catalytic mineralization-recovery cycles can take place without a reduction in the catalytic properties of the iron oxide nanocatalyst. |
doi_str_mv | 10.1016/j.desal.2010.05.016 |
format | article |
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2O
2/iron oxide mineralization process was investigated. The particle size and morphology of iron oxide particles obtained from TEM (Transmission Electron Microscopy) images and DLS (Dynamic Light Scattering) measurements, indicate the formation of a rod-like morphology with an average length of 50
±
10
nm. An electron diffraction pattern identified the particles as either α-FeOOH or β-FeOOH. Stability of iron oxide nanoparticles in organic model compound solutions was studied as a function of pH solution and was correlated with average size. The optimal pH for maximum mineralization in the H
2O
2/iron oxide system was found to be 2.8. Finally, results indicated that at least seven stages of catalytic mineralization-recovery cycles can take place without a reduction in the catalytic properties of the iron oxide nanocatalyst.</description><identifier>ISSN: 0011-9164</identifier><identifier>EISSN: 1873-4464</identifier><identifier>DOI: 10.1016/j.desal.2010.05.016</identifier><identifier>CODEN: DSLNAH</identifier><language>eng</language><publisher>Amsterdam: Elsevier B.V</publisher><subject>AOP ; Applied sciences ; Catalysis ; Catalysts ; Catalytic reactions ; Chemical engineering ; Chemistry ; Exact sciences and technology ; Fenton process ; General and physical chemistry ; Iron oxide ; Iron oxides ; Mathematical models ; Mineralization ; Morphology ; Nanomaterials ; Nanostructure ; Pollution ; Reactors ; Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry ; Total organic carbon (TOC)</subject><ispartof>Desalination, 2010-11, Vol.262 (1), p.15-20</ispartof><rights>2010 Elsevier B.V.</rights><rights>2015 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c406t-46aada1190bb2da202d451fb56d980ac16019c0999ea8ac94154e0ece7672233</citedby><cites>FETCH-LOGICAL-c406t-46aada1190bb2da202d451fb56d980ac16019c0999ea8ac94154e0ece7672233</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27923,27924</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=23270061$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Bach, Altai</creatorcontrib><creatorcontrib>Zach-Maor, Adva</creatorcontrib><creatorcontrib>Semiat, Raphael</creatorcontrib><title>Characterization of iron oxide nanocatalyst in mineralization processes</title><title>Desalination</title><description>The reuse of iron oxide nanoparticles as a catalyst of organic matter in the H
2O
2/iron oxide mineralization process was investigated. The particle size and morphology of iron oxide particles obtained from TEM (Transmission Electron Microscopy) images and DLS (Dynamic Light Scattering) measurements, indicate the formation of a rod-like morphology with an average length of 50
±
10
nm. An electron diffraction pattern identified the particles as either α-FeOOH or β-FeOOH. Stability of iron oxide nanoparticles in organic model compound solutions was studied as a function of pH solution and was correlated with average size. The optimal pH for maximum mineralization in the H
2O
2/iron oxide system was found to be 2.8. Finally, results indicated that at least seven stages of catalytic mineralization-recovery cycles can take place without a reduction in the catalytic properties of the iron oxide nanocatalyst.</description><subject>AOP</subject><subject>Applied sciences</subject><subject>Catalysis</subject><subject>Catalysts</subject><subject>Catalytic reactions</subject><subject>Chemical engineering</subject><subject>Chemistry</subject><subject>Exact sciences and technology</subject><subject>Fenton process</subject><subject>General and physical chemistry</subject><subject>Iron oxide</subject><subject>Iron oxides</subject><subject>Mathematical models</subject><subject>Mineralization</subject><subject>Morphology</subject><subject>Nanomaterials</subject><subject>Nanostructure</subject><subject>Pollution</subject><subject>Reactors</subject><subject>Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry</subject><subject>Total organic carbon (TOC)</subject><issn>0011-9164</issn><issn>1873-4464</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2010</creationdate><recordtype>article</recordtype><recordid>eNp9kDFPwzAQhS0EEqXwC1iyIKaUs-M48cCAKihIlVi6W1fnIlylTrFTRPn1uLQwMp3u6bv3dI-xaw4TDlzdrSYNRewmApIC5SRpJ2zE66rIpVTylI0AOM81V_KcXcS4SqvQRTFis-kbBrQDBfeFg-t91reZC_v56RrKPPre4oDdLg6Z89naeQrY_cKb0FuKkeIlO2uxi3R1nGO2eHpcTJ_z-evsZfowz60ENeRSITbIuYblUjQoQDSy5O2yVI2uAS1XwLUFrTVhjVZLXkoCslSpSoiiGLPbg20Kft9SHMzaRUtdh576bTSVEkLVZS0TWRxIG_oYA7VmE9waw85wMPvSzMr8lGb2pRkoTdLS1c3RH6PFrg3orYt_p6IQFYDiibs_cJR-_XAUTLSOvKXGBbKDaXr3b843xTOD6w</recordid><startdate>20101115</startdate><enddate>20101115</enddate><creator>Bach, Altai</creator><creator>Zach-Maor, Adva</creator><creator>Semiat, Raphael</creator><general>Elsevier B.V</general><general>Elsevier</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>8FD</scope><scope>FR3</scope><scope>KR7</scope></search><sort><creationdate>20101115</creationdate><title>Characterization of iron oxide nanocatalyst in mineralization processes</title><author>Bach, Altai ; Zach-Maor, Adva ; Semiat, Raphael</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c406t-46aada1190bb2da202d451fb56d980ac16019c0999ea8ac94154e0ece7672233</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2010</creationdate><topic>AOP</topic><topic>Applied sciences</topic><topic>Catalysis</topic><topic>Catalysts</topic><topic>Catalytic reactions</topic><topic>Chemical engineering</topic><topic>Chemistry</topic><topic>Exact sciences and technology</topic><topic>Fenton process</topic><topic>General and physical chemistry</topic><topic>Iron oxide</topic><topic>Iron oxides</topic><topic>Mathematical models</topic><topic>Mineralization</topic><topic>Morphology</topic><topic>Nanomaterials</topic><topic>Nanostructure</topic><topic>Pollution</topic><topic>Reactors</topic><topic>Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry</topic><topic>Total organic carbon (TOC)</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Bach, Altai</creatorcontrib><creatorcontrib>Zach-Maor, Adva</creatorcontrib><creatorcontrib>Semiat, Raphael</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Technology Research Database</collection><collection>Engineering Research Database</collection><collection>Civil Engineering Abstracts</collection><jtitle>Desalination</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Bach, Altai</au><au>Zach-Maor, Adva</au><au>Semiat, Raphael</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Characterization of iron oxide nanocatalyst in mineralization processes</atitle><jtitle>Desalination</jtitle><date>2010-11-15</date><risdate>2010</risdate><volume>262</volume><issue>1</issue><spage>15</spage><epage>20</epage><pages>15-20</pages><issn>0011-9164</issn><eissn>1873-4464</eissn><coden>DSLNAH</coden><abstract>The reuse of iron oxide nanoparticles as a catalyst of organic matter in the H
2O
2/iron oxide mineralization process was investigated. The particle size and morphology of iron oxide particles obtained from TEM (Transmission Electron Microscopy) images and DLS (Dynamic Light Scattering) measurements, indicate the formation of a rod-like morphology with an average length of 50
±
10
nm. An electron diffraction pattern identified the particles as either α-FeOOH or β-FeOOH. Stability of iron oxide nanoparticles in organic model compound solutions was studied as a function of pH solution and was correlated with average size. The optimal pH for maximum mineralization in the H
2O
2/iron oxide system was found to be 2.8. Finally, results indicated that at least seven stages of catalytic mineralization-recovery cycles can take place without a reduction in the catalytic properties of the iron oxide nanocatalyst.</abstract><cop>Amsterdam</cop><pub>Elsevier B.V</pub><doi>10.1016/j.desal.2010.05.016</doi><tpages>6</tpages></addata></record> |
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subjects | AOP Applied sciences Catalysis Catalysts Catalytic reactions Chemical engineering Chemistry Exact sciences and technology Fenton process General and physical chemistry Iron oxide Iron oxides Mathematical models Mineralization Morphology Nanomaterials Nanostructure Pollution Reactors Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry Total organic carbon (TOC) |
title | Characterization of iron oxide nanocatalyst in mineralization processes |
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