C−H and C−C Bond Activation of Primary Amines through Dehydrogenation and Transimination

Dehydrogenation and subsequent transimination of primary amines offer a new pathway for C−H bond activation, ortho-alkylation, and C−C bond activation to afford a variety of ketones in the reaction of 1-alkene by a cocatalyt system of Rh(I) and 2-amino-3-picoline.

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Bibliographic Details
Published in:Organic letters 2001-03, Vol.3 (5), p.785-787
Main Authors: Jun, Chul-Ho, Chung, Kwan-Yong, Hong, Jun-Bae
Format: Article
Language:English
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Summary:Dehydrogenation and subsequent transimination of primary amines offer a new pathway for C−H bond activation, ortho-alkylation, and C−C bond activation to afford a variety of ketones in the reaction of 1-alkene by a cocatalyt system of Rh(I) and 2-amino-3-picoline.
ISSN:1523-7060
1523-7052
DOI:10.1021/ol015563+