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Diterpenoid Alkaloids from Delphinium davisii
Three new hetisane-type diterpenoid alkaloids, davisinol (6), 18-benzoyldavisinol (7), and Davisin (9) have been isolated from Delphinium davisii Munz. and their structures established by detailed spectroscopic studies. Accurate 1H- and 13C-NMR assignments have been made for kobusine (8), a related...
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| Published in: | Journal of natural products (Washington, D.C.) D.C.), 1996-04, Vol.59 (4), p.360-366 |
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| Main Authors: | , , , , , , , , , |
| Format: | Article |
| Language: | English |
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| cited_by | cdi_FETCH-LOGICAL-a396t-5e0a8c7fcba19df617b275ad1e83b91ef05392d3a46fbd6dadcc3da86e0100513 |
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| cites | cdi_FETCH-LOGICAL-a396t-5e0a8c7fcba19df617b275ad1e83b91ef05392d3a46fbd6dadcc3da86e0100513 |
| container_end_page | 366 |
| container_issue | 4 |
| container_start_page | 360 |
| container_title | Journal of natural products (Washington, D.C.) |
| container_volume | 59 |
| creator | Ulubelen, Ayhan Desai, Haridutt K Srivastava, Santosh K Hart, Bradley P Park, Jong-C Joshi, Balawant S Pelletier, S. William Meriçli, Ali H Meriçli, Filiz Ilarslan, Resit |
| description | Three new hetisane-type diterpenoid alkaloids, davisinol (6), 18-benzoyldavisinol (7), and Davisin (9) have been isolated from Delphinium davisii Munz. and their structures established by detailed spectroscopic studies. Accurate 1H- and 13C-NMR assignments have been made for kobusine (8), a related hetisane-type alkaloid, and karakoline (5), a norditerpenoid alkaloid. The known norditerpenoid alkaloids 14-acetylperegrine (4), 6-deacetylperegrine (3), and karakoline (5) and the diterpenoid alkaloids hetisine and hetisinone were also isolated. |
| doi_str_mv | 10.1021/np960215f |
| format | article |
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William ; Meriçli, Ali H ; Meriçli, Filiz ; Ilarslan, Resit</creator><creatorcontrib>Ulubelen, Ayhan ; Desai, Haridutt K ; Srivastava, Santosh K ; Hart, Bradley P ; Park, Jong-C ; Joshi, Balawant S ; Pelletier, S. William ; Meriçli, Ali H ; Meriçli, Filiz ; Ilarslan, Resit</creatorcontrib><description>Three new hetisane-type diterpenoid alkaloids, davisinol (6), 18-benzoyldavisinol (7), and Davisin (9) have been isolated from Delphinium davisii Munz. and their structures established by detailed spectroscopic studies. Accurate 1H- and 13C-NMR assignments have been made for kobusine (8), a related hetisane-type alkaloid, and karakoline (5), a norditerpenoid alkaloid. The known norditerpenoid alkaloids 14-acetylperegrine (4), 6-deacetylperegrine (3), and karakoline (5) and the diterpenoid alkaloids hetisine and hetisinone were also isolated.</description><identifier>ISSN: 0163-3864</identifier><identifier>EISSN: 1520-6025</identifier><identifier>DOI: 10.1021/np960215f</identifier><identifier>PMID: 8699181</identifier><identifier>CODEN: JNPRDF</identifier><language>eng</language><publisher>Washington, DC: American Chemical Society</publisher><subject>14-acetylperegrine ; 18-benzoyldavisinol ; 6-deacetylperegrine ; ALCALOIDE ; ALCALOIDES ; ALKALOIDS ; Alkaloids - chemistry ; Alkaloids - isolation & purification ; Biological and medical sciences ; Carbohydrate Sequence ; CHEMICAL COMPOSITION ; Chromatography, Thin Layer ; COMPOSICION QUIMICA ; COMPOSITION CHIMIQUE ; davisin ; davisinol ; DELPHINIUM ; Diterpenes - chemistry ; Diterpenes - isolation & purification ; DITERPENOIDE ; DITERPENOIDS ; DITERPENOS ; DRUG PLANTS ; ESPECTROMETRIA ; General pharmacology ; hetisine ; hetisinone ; karakoline ; leobusine ; Magnetic Resonance Spectroscopy ; Medical sciences ; MOLECULAR CONFORMATION ; Molecular Sequence Data ; molecular structure ; Pharmacognosy. Homeopathy. Health food ; Pharmacology. Drug treatments ; Plant Leaves - chemistry ; PLANTAS MEDICINALES ; PLANTE MEDICINALE ; Plants, Medicinal - chemistry ; SPECTRAL ANALYSIS ; SPECTROMETRIE ; SPECTROMETRY ; Spectrophotometry, Infrared ; TURKEY ; TURQUIA ; TURQUIE</subject><ispartof>Journal of natural products (Washington, D.C.), 1996-04, Vol.59 (4), p.360-366</ispartof><rights>Copyright © 1996 American Chemical Society and American Society of Pharmacognosy</rights><rights>1996 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-a396t-5e0a8c7fcba19df617b275ad1e83b91ef05392d3a46fbd6dadcc3da86e0100513</citedby><cites>FETCH-LOGICAL-a396t-5e0a8c7fcba19df617b275ad1e83b91ef05392d3a46fbd6dadcc3da86e0100513</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=3214392$$DView record in Pascal Francis$$Hfree_for_read</backlink><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/8699181$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Ulubelen, Ayhan</creatorcontrib><creatorcontrib>Desai, Haridutt K</creatorcontrib><creatorcontrib>Srivastava, Santosh K</creatorcontrib><creatorcontrib>Hart, Bradley P</creatorcontrib><creatorcontrib>Park, Jong-C</creatorcontrib><creatorcontrib>Joshi, Balawant S</creatorcontrib><creatorcontrib>Pelletier, S. William</creatorcontrib><creatorcontrib>Meriçli, Ali H</creatorcontrib><creatorcontrib>Meriçli, Filiz</creatorcontrib><creatorcontrib>Ilarslan, Resit</creatorcontrib><title>Diterpenoid Alkaloids from Delphinium davisii</title><title>Journal of natural products (Washington, D.C.)</title><addtitle>J. Nat. Prod</addtitle><description>Three new hetisane-type diterpenoid alkaloids, davisinol (6), 18-benzoyldavisinol (7), and Davisin (9) have been isolated from Delphinium davisii Munz. and their structures established by detailed spectroscopic studies. Accurate 1H- and 13C-NMR assignments have been made for kobusine (8), a related hetisane-type alkaloid, and karakoline (5), a norditerpenoid alkaloid. The known norditerpenoid alkaloids 14-acetylperegrine (4), 6-deacetylperegrine (3), and karakoline (5) and the diterpenoid alkaloids hetisine and hetisinone were also isolated.</description><subject>14-acetylperegrine</subject><subject>18-benzoyldavisinol</subject><subject>6-deacetylperegrine</subject><subject>ALCALOIDE</subject><subject>ALCALOIDES</subject><subject>ALKALOIDS</subject><subject>Alkaloids - chemistry</subject><subject>Alkaloids - isolation & purification</subject><subject>Biological and medical sciences</subject><subject>Carbohydrate Sequence</subject><subject>CHEMICAL COMPOSITION</subject><subject>Chromatography, Thin Layer</subject><subject>COMPOSICION QUIMICA</subject><subject>COMPOSITION CHIMIQUE</subject><subject>davisin</subject><subject>davisinol</subject><subject>DELPHINIUM</subject><subject>Diterpenes - chemistry</subject><subject>Diterpenes - isolation & purification</subject><subject>DITERPENOIDE</subject><subject>DITERPENOIDS</subject><subject>DITERPENOS</subject><subject>DRUG PLANTS</subject><subject>ESPECTROMETRIA</subject><subject>General pharmacology</subject><subject>hetisine</subject><subject>hetisinone</subject><subject>karakoline</subject><subject>leobusine</subject><subject>Magnetic Resonance Spectroscopy</subject><subject>Medical sciences</subject><subject>MOLECULAR CONFORMATION</subject><subject>Molecular Sequence Data</subject><subject>molecular structure</subject><subject>Pharmacognosy. Homeopathy. Health food</subject><subject>Pharmacology. Drug treatments</subject><subject>Plant Leaves - chemistry</subject><subject>PLANTAS MEDICINALES</subject><subject>PLANTE MEDICINALE</subject><subject>Plants, Medicinal - chemistry</subject><subject>SPECTRAL ANALYSIS</subject><subject>SPECTROMETRIE</subject><subject>SPECTROMETRY</subject><subject>Spectrophotometry, Infrared</subject><subject>TURKEY</subject><subject>TURQUIA</subject><subject>TURQUIE</subject><issn>0163-3864</issn><issn>1520-6025</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1996</creationdate><recordtype>article</recordtype><recordid>eNptkE1LJDEQhoMoOut68CoIc3AXPLRWOp105zjofijiCjOeQ3U-NNpfJtPL7r830sOcPFUVz8NL8RJyTOGCQk4vu0GKNLnbITPKc8jSxXfJDKhgGatEcUC-xPgCAAwk3yf7lZCSVnRGsmu_tmGwXe_NfNG8YpOWOHehb-fXthmefefHdm7wr4_efyV7DptojzbzkDz-_LG6-p3d_fl1c7W4y5BJsc64Bax06XSNVBonaFnnJUdDbcVqSa0DzmRuGBbC1UYYNFozg5WwQAE4ZYfk-5Q7hP5ttHGtWh-1bRrsbD9GVVbAhGBFEs8nUYc-xmCdGoJvMfxXFNRHNWpbTXJPN6Fj3VqzNTddJH624Rg1Ni5gp33caiynRfo6admk-bi2_7YYw6sSJSu5Wj0sVTJXy-oW1H3yTybfYa_wKaTIx6UUlEPBEvw2QdRRvfRj6FKtn_z-Dofyjbs</recordid><startdate>19960401</startdate><enddate>19960401</enddate><creator>Ulubelen, Ayhan</creator><creator>Desai, Haridutt K</creator><creator>Srivastava, Santosh K</creator><creator>Hart, Bradley P</creator><creator>Park, Jong-C</creator><creator>Joshi, Balawant S</creator><creator>Pelletier, S. William</creator><creator>Meriçli, Ali H</creator><creator>Meriçli, Filiz</creator><creator>Ilarslan, Resit</creator><general>American Chemical Society</general><general>American Society of Pharmacognosy</general><scope>FBQ</scope><scope>BSCLL</scope><scope>IQODW</scope><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope></search><sort><creationdate>19960401</creationdate><title>Diterpenoid Alkaloids from Delphinium davisii</title><author>Ulubelen, Ayhan ; Desai, Haridutt K ; Srivastava, Santosh K ; Hart, Bradley P ; Park, Jong-C ; Joshi, Balawant S ; Pelletier, S. William ; Meriçli, Ali H ; Meriçli, Filiz ; Ilarslan, Resit</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a396t-5e0a8c7fcba19df617b275ad1e83b91ef05392d3a46fbd6dadcc3da86e0100513</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1996</creationdate><topic>14-acetylperegrine</topic><topic>18-benzoyldavisinol</topic><topic>6-deacetylperegrine</topic><topic>ALCALOIDE</topic><topic>ALCALOIDES</topic><topic>ALKALOIDS</topic><topic>Alkaloids - chemistry</topic><topic>Alkaloids - isolation & purification</topic><topic>Biological and medical sciences</topic><topic>Carbohydrate Sequence</topic><topic>CHEMICAL COMPOSITION</topic><topic>Chromatography, Thin Layer</topic><topic>COMPOSICION QUIMICA</topic><topic>COMPOSITION CHIMIQUE</topic><topic>davisin</topic><topic>davisinol</topic><topic>DELPHINIUM</topic><topic>Diterpenes - chemistry</topic><topic>Diterpenes - isolation & purification</topic><topic>DITERPENOIDE</topic><topic>DITERPENOIDS</topic><topic>DITERPENOS</topic><topic>DRUG PLANTS</topic><topic>ESPECTROMETRIA</topic><topic>General pharmacology</topic><topic>hetisine</topic><topic>hetisinone</topic><topic>karakoline</topic><topic>leobusine</topic><topic>Magnetic Resonance Spectroscopy</topic><topic>Medical sciences</topic><topic>MOLECULAR CONFORMATION</topic><topic>Molecular Sequence Data</topic><topic>molecular structure</topic><topic>Pharmacognosy. Homeopathy. Health food</topic><topic>Pharmacology. Drug treatments</topic><topic>Plant Leaves - chemistry</topic><topic>PLANTAS MEDICINALES</topic><topic>PLANTE MEDICINALE</topic><topic>Plants, Medicinal - chemistry</topic><topic>SPECTRAL ANALYSIS</topic><topic>SPECTROMETRIE</topic><topic>SPECTROMETRY</topic><topic>Spectrophotometry, Infrared</topic><topic>TURKEY</topic><topic>TURQUIA</topic><topic>TURQUIE</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Ulubelen, Ayhan</creatorcontrib><creatorcontrib>Desai, Haridutt K</creatorcontrib><creatorcontrib>Srivastava, Santosh K</creatorcontrib><creatorcontrib>Hart, Bradley P</creatorcontrib><creatorcontrib>Park, Jong-C</creatorcontrib><creatorcontrib>Joshi, Balawant S</creatorcontrib><creatorcontrib>Pelletier, S. William</creatorcontrib><creatorcontrib>Meriçli, Ali H</creatorcontrib><creatorcontrib>Meriçli, Filiz</creatorcontrib><creatorcontrib>Ilarslan, Resit</creatorcontrib><collection>AGRIS</collection><collection>Istex</collection><collection>Pascal-Francis</collection><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><jtitle>Journal of natural products (Washington, D.C.)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Ulubelen, Ayhan</au><au>Desai, Haridutt K</au><au>Srivastava, Santosh K</au><au>Hart, Bradley P</au><au>Park, Jong-C</au><au>Joshi, Balawant S</au><au>Pelletier, S. William</au><au>Meriçli, Ali H</au><au>Meriçli, Filiz</au><au>Ilarslan, Resit</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Diterpenoid Alkaloids from Delphinium davisii</atitle><jtitle>Journal of natural products (Washington, D.C.)</jtitle><addtitle>J. Nat. Prod</addtitle><date>1996-04-01</date><risdate>1996</risdate><volume>59</volume><issue>4</issue><spage>360</spage><epage>366</epage><pages>360-366</pages><issn>0163-3864</issn><eissn>1520-6025</eissn><coden>JNPRDF</coden><abstract>Three new hetisane-type diterpenoid alkaloids, davisinol (6), 18-benzoyldavisinol (7), and Davisin (9) have been isolated from Delphinium davisii Munz. and their structures established by detailed spectroscopic studies. Accurate 1H- and 13C-NMR assignments have been made for kobusine (8), a related hetisane-type alkaloid, and karakoline (5), a norditerpenoid alkaloid. The known norditerpenoid alkaloids 14-acetylperegrine (4), 6-deacetylperegrine (3), and karakoline (5) and the diterpenoid alkaloids hetisine and hetisinone were also isolated.</abstract><cop>Washington, DC</cop><cop>Glendale, AZ</cop><pub>American Chemical Society</pub><pmid>8699181</pmid><doi>10.1021/np960215f</doi><tpages>7</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0163-3864 |
| ispartof | Journal of natural products (Washington, D.C.), 1996-04, Vol.59 (4), p.360-366 |
| issn | 0163-3864 1520-6025 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_78036634 |
| source | American Chemical Society:Jisc Collections:American Chemical Society Read & Publish Agreement 2022-2024 (Reading list) |
| subjects | 14-acetylperegrine 18-benzoyldavisinol 6-deacetylperegrine ALCALOIDE ALCALOIDES ALKALOIDS Alkaloids - chemistry Alkaloids - isolation & purification Biological and medical sciences Carbohydrate Sequence CHEMICAL COMPOSITION Chromatography, Thin Layer COMPOSICION QUIMICA COMPOSITION CHIMIQUE davisin davisinol DELPHINIUM Diterpenes - chemistry Diterpenes - isolation & purification DITERPENOIDE DITERPENOIDS DITERPENOS DRUG PLANTS ESPECTROMETRIA General pharmacology hetisine hetisinone karakoline leobusine Magnetic Resonance Spectroscopy Medical sciences MOLECULAR CONFORMATION Molecular Sequence Data molecular structure Pharmacognosy. Homeopathy. Health food Pharmacology. Drug treatments Plant Leaves - chemistry PLANTAS MEDICINALES PLANTE MEDICINALE Plants, Medicinal - chemistry SPECTRAL ANALYSIS SPECTROMETRIE SPECTROMETRY Spectrophotometry, Infrared TURKEY TURQUIA TURQUIE |
| title | Diterpenoid Alkaloids from Delphinium davisii |
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