Chlorido(η5-cyclopentadienyl)bis(dimethylamido)titanium, [TiCl(η5-C5H5)(NMe2)2]

The title complex, [Ti(C5H5)(C2H6N)2Cl], exhibits two nearly planar dimethylamide groups oriented approximately perpendicular to each other. The Ti→cyclopentadienyl centroid vector lies nearly in the plane of one of the dimethylamide groups. Long‐range contacts between Ti—Cl and cyclopentadienyl H—C...

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Bibliographic Details
Published in:Acta crystallographica. Section C, Crystal structure communications Crystal structure communications, 2010-07, Vol.66 (7), p.m191-m193
Main Authors: Chapin, Brette M., Hughs, Lauren D., Golen, James A., Rheingold, Arnold L., Johnson, Adam R.
Format: Article
Language:English
Subjects:
Centroids
Crystal structure
Crystallography
Mathematical analysis
Order disorder
Planes
Titanium
Vectors (mathematics)
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Summary:The title complex, [Ti(C5H5)(C2H6N)2Cl], exhibits two nearly planar dimethylamide groups oriented approximately perpendicular to each other. The Ti→cyclopentadienyl centroid vector lies nearly in the plane of one of the dimethylamide groups. Long‐range contacts between Ti—Cl and cyclopentadienyl H—C groups give rise to geometric ordering in the extended solid.
ISSN:0108-2701
1600-5759
DOI:10.1107/S0108270110023176