Synthesis of brominated tetrathiafulvalenes via phosphite-mediated cross-coupling

The synthesis of polybrominated tetrathiafulvalenes (TTF–Br n , 2– 4) containing 2–4 bromine atoms via phosphite-mediated cross-coupling of bromo-substituted 1,3-dithiole-2-thiones and 1,3-dithiole-2-ones is reported.

Saved in:
Bibliographic Details
Published in:Synthetic metals 2010-08, Vol.160 (15), p.1797-1799
Main Authors: Alberola, Antonio, Bosch-Navarro, Concha, Gaviña, Pablo, Tatay, Sergio
Format: Article
Language:English
Subjects:
Brominated tetrathiafulvalenes
Bromination
Bromine
Chemistry
Exact sciences and technology
Halogenation
Heterocyclic compounds
Heterocyclic compounds with o, s, se, te hetero atom and condensed derivatives
Lithiation
Organic chemistry
Phosphite cross-coupling
Preparations and properties
Synthesis
Synthetic metals
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:The synthesis of polybrominated tetrathiafulvalenes (TTF–Br n , 2– 4) containing 2–4 bromine atoms via phosphite-mediated cross-coupling of bromo-substituted 1,3-dithiole-2-thiones and 1,3-dithiole-2-ones is reported.
ISSN:0379-6779
1879-3290
DOI:10.1016/j.synthmet.2010.06.001