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Preparation and characterization of polyaniline film on stainless steel by electrochemical polymerization as a counter electrode of DSSC
Polyaniline (PANI) films were electrodeposited on stainless steel 304 (SS) from 0.5 M H 2SO 4 solution containing 0.3 M aniline by potentiostatic techniques to prepare a low cost and non-fragile counter electrode in dye-sensitized solar cell (DSSC). The compact layer, micro-particles, nanorods and f...
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| Published in: | Synthetic metals 2010-06, Vol.160 (11), p.1167-1172 |
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| Language: | English |
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| cites | cdi_FETCH-LOGICAL-c440t-2b97bc1b07afa693d23a8092d2930132f2e09fc89e431d8345ce3c99f61a5ba03 |
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| container_title | Synthetic metals |
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| creator | Qin, Qi Tao, Jie Yang, Yan |
| description | Polyaniline (PANI) films were electrodeposited on stainless steel 304 (SS) from 0.5
M H
2SO
4 solution containing 0.3
M aniline by potentiostatic techniques to prepare a low cost and non-fragile counter electrode in dye-sensitized solar cell (DSSC). The compact layer, micro-particles, nanorods and fibrils were observed on the top of PANI films with different applied potentials (
E
appl) by SEM. Then the conductivity and electrochemical test illuminated that a polyaniline film with the highest conductivity and best electrocatalytic activity for I
3
−/I
− reaction was electrodeposited at 1.0
V
E
appl. Finally, the photoelectric measurement showed that the energy conversion efficiency of DSSC with the PANI electrode was increased with the
E
appl decreasing. And the efficiency of DSSC with PANI counter electrode at 1.0
V was higher than that with Pt electrode, owing to the loosely porous structure, high conductivity and excellent catalytic activity of PANI electrode. |
| doi_str_mv | 10.1016/j.synthmet.2010.03.003 |
| format | article |
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M H
2SO
4 solution containing 0.3
M aniline by potentiostatic techniques to prepare a low cost and non-fragile counter electrode in dye-sensitized solar cell (DSSC). The compact layer, micro-particles, nanorods and fibrils were observed on the top of PANI films with different applied potentials (
E
appl) by SEM. Then the conductivity and electrochemical test illuminated that a polyaniline film with the highest conductivity and best electrocatalytic activity for I
3
−/I
− reaction was electrodeposited at 1.0
V
E
appl. Finally, the photoelectric measurement showed that the energy conversion efficiency of DSSC with the PANI electrode was increased with the
E
appl decreasing. And the efficiency of DSSC with PANI counter electrode at 1.0
V was higher than that with Pt electrode, owing to the loosely porous structure, high conductivity and excellent catalytic activity of PANI electrode.</description><identifier>ISSN: 0379-6779</identifier><identifier>EISSN: 1879-3290</identifier><identifier>DOI: 10.1016/j.synthmet.2010.03.003</identifier><identifier>CODEN: SYMEDZ</identifier><language>eng</language><publisher>Amsterdam: Elsevier B.V</publisher><subject>Applied sciences ; Austenitic stainless steels ; Dye-sensitized solar cell ; Dyes ; Electrochemical ; Electrodes ; Energy ; Energy conversion efficiency ; Exact sciences and technology ; Nanorods ; Natural energy ; Photoelectricity ; Photovoltaic conversion ; Physicochemistry of polymers ; Polyaniline ; Polyanilines ; Polymerization ; Polymers and radiations ; Potentiostatic ; Solar cells ; Solar cells. Photoelectrochemical cells ; Solar energy ; Stainless steel ; Stainless steels</subject><ispartof>Synthetic metals, 2010-06, Vol.160 (11), p.1167-1172</ispartof><rights>2010 Elsevier B.V.</rights><rights>2015 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c440t-2b97bc1b07afa693d23a8092d2930132f2e09fc89e431d8345ce3c99f61a5ba03</citedby><cites>FETCH-LOGICAL-c440t-2b97bc1b07afa693d23a8092d2930132f2e09fc89e431d8345ce3c99f61a5ba03</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=22923624$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Qin, Qi</creatorcontrib><creatorcontrib>Tao, Jie</creatorcontrib><creatorcontrib>Yang, Yan</creatorcontrib><title>Preparation and characterization of polyaniline film on stainless steel by electrochemical polymerization as a counter electrode of DSSC</title><title>Synthetic metals</title><description>Polyaniline (PANI) films were electrodeposited on stainless steel 304 (SS) from 0.5
M H
2SO
4 solution containing 0.3
M aniline by potentiostatic techniques to prepare a low cost and non-fragile counter electrode in dye-sensitized solar cell (DSSC). The compact layer, micro-particles, nanorods and fibrils were observed on the top of PANI films with different applied potentials (
E
appl) by SEM. Then the conductivity and electrochemical test illuminated that a polyaniline film with the highest conductivity and best electrocatalytic activity for I
3
−/I
− reaction was electrodeposited at 1.0
V
E
appl. Finally, the photoelectric measurement showed that the energy conversion efficiency of DSSC with the PANI electrode was increased with the
E
appl decreasing. And the efficiency of DSSC with PANI counter electrode at 1.0
V was higher than that with Pt electrode, owing to the loosely porous structure, high conductivity and excellent catalytic activity of PANI electrode.</description><subject>Applied sciences</subject><subject>Austenitic stainless steels</subject><subject>Dye-sensitized solar cell</subject><subject>Dyes</subject><subject>Electrochemical</subject><subject>Electrodes</subject><subject>Energy</subject><subject>Energy conversion efficiency</subject><subject>Exact sciences and technology</subject><subject>Nanorods</subject><subject>Natural energy</subject><subject>Photoelectricity</subject><subject>Photovoltaic conversion</subject><subject>Physicochemistry of polymers</subject><subject>Polyaniline</subject><subject>Polyanilines</subject><subject>Polymerization</subject><subject>Polymers and radiations</subject><subject>Potentiostatic</subject><subject>Solar cells</subject><subject>Solar cells. Photoelectrochemical cells</subject><subject>Solar energy</subject><subject>Stainless steel</subject><subject>Stainless steels</subject><issn>0379-6779</issn><issn>1879-3290</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2010</creationdate><recordtype>article</recordtype><recordid>eNqFkE9vEzEQxS0EEqHwFZAviFPSsb3ZXd9A4V-lSq3U9mzNeseKI68d7A1S-AR8bBzSwpGTx0_vvdH8GHsrYCVAtJe7VTnGeTvRvJJQRVArAPWMLUTf6aWSGp6zBag6t12nX7JXpewAQGi5XrBft5n2mHH2KXKMI7fb-rMzZf_zLCbH9ykcMfrgI3Hnw8SrXGb0MVApdSIKfDhyCmTnnOyWJm8x_IlN_4qwcOQ2HWItf_KOdOr_dHe3ec1eOAyF3jy-F-zhy-f7zbfl9c3Xq83H66VtGpiXctDdYMUAHTpstRqlwh60HKVWIJR0kkA722tqlBh71awtKau1awWuBwR1wd6fe_c5fT9Qmc3ki6UQMFI6FNP1nZRt056c7dlpcyolkzP77CfMRyPAnMibnXkib07kDShTydfgu8cVWCoHlzFaX_6mpdRStbKpvg9nH9V7f3jKplhP0dLoc6VjxuT_t-o3SISgjQ</recordid><startdate>20100601</startdate><enddate>20100601</enddate><creator>Qin, Qi</creator><creator>Tao, Jie</creator><creator>Yang, Yan</creator><general>Elsevier B.V</general><general>Elsevier</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>20100601</creationdate><title>Preparation and characterization of polyaniline film on stainless steel by electrochemical polymerization as a counter electrode of DSSC</title><author>Qin, Qi ; Tao, Jie ; Yang, Yan</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c440t-2b97bc1b07afa693d23a8092d2930132f2e09fc89e431d8345ce3c99f61a5ba03</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2010</creationdate><topic>Applied sciences</topic><topic>Austenitic stainless steels</topic><topic>Dye-sensitized solar cell</topic><topic>Dyes</topic><topic>Electrochemical</topic><topic>Electrodes</topic><topic>Energy</topic><topic>Energy conversion efficiency</topic><topic>Exact sciences and technology</topic><topic>Nanorods</topic><topic>Natural energy</topic><topic>Photoelectricity</topic><topic>Photovoltaic conversion</topic><topic>Physicochemistry of polymers</topic><topic>Polyaniline</topic><topic>Polyanilines</topic><topic>Polymerization</topic><topic>Polymers and radiations</topic><topic>Potentiostatic</topic><topic>Solar cells</topic><topic>Solar cells. Photoelectrochemical cells</topic><topic>Solar energy</topic><topic>Stainless steel</topic><topic>Stainless steels</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Qin, Qi</creatorcontrib><creatorcontrib>Tao, Jie</creatorcontrib><creatorcontrib>Yang, Yan</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Synthetic metals</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Qin, Qi</au><au>Tao, Jie</au><au>Yang, Yan</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Preparation and characterization of polyaniline film on stainless steel by electrochemical polymerization as a counter electrode of DSSC</atitle><jtitle>Synthetic metals</jtitle><date>2010-06-01</date><risdate>2010</risdate><volume>160</volume><issue>11</issue><spage>1167</spage><epage>1172</epage><pages>1167-1172</pages><issn>0379-6779</issn><eissn>1879-3290</eissn><coden>SYMEDZ</coden><abstract>Polyaniline (PANI) films were electrodeposited on stainless steel 304 (SS) from 0.5
M H
2SO
4 solution containing 0.3
M aniline by potentiostatic techniques to prepare a low cost and non-fragile counter electrode in dye-sensitized solar cell (DSSC). The compact layer, micro-particles, nanorods and fibrils were observed on the top of PANI films with different applied potentials (
E
appl) by SEM. Then the conductivity and electrochemical test illuminated that a polyaniline film with the highest conductivity and best electrocatalytic activity for I
3
−/I
− reaction was electrodeposited at 1.0
V
E
appl. Finally, the photoelectric measurement showed that the energy conversion efficiency of DSSC with the PANI electrode was increased with the
E
appl decreasing. And the efficiency of DSSC with PANI counter electrode at 1.0
V was higher than that with Pt electrode, owing to the loosely porous structure, high conductivity and excellent catalytic activity of PANI electrode.</abstract><cop>Amsterdam</cop><pub>Elsevier B.V</pub><doi>10.1016/j.synthmet.2010.03.003</doi><tpages>6</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0379-6779 |
| ispartof | Synthetic metals, 2010-06, Vol.160 (11), p.1167-1172 |
| issn | 0379-6779 1879-3290 |
| language | eng |
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| source | ScienceDirect Freedom Collection |
| subjects | Applied sciences Austenitic stainless steels Dye-sensitized solar cell Dyes Electrochemical Electrodes Energy Energy conversion efficiency Exact sciences and technology Nanorods Natural energy Photoelectricity Photovoltaic conversion Physicochemistry of polymers Polyaniline Polyanilines Polymerization Polymers and radiations Potentiostatic Solar cells Solar cells. Photoelectrochemical cells Solar energy Stainless steel Stainless steels |
| title | Preparation and characterization of polyaniline film on stainless steel by electrochemical polymerization as a counter electrode of DSSC |
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