A New Reaction Sequence Involving Palladium-Catalyzed Unsymmetrical Aryl Coupling

Biphenylylalkenes containing an ortho substituent in one ring and a different ortho-, meta-, or para-substituent in the other are prepared in satisfactory yield from an ortho-substituted aryl iodide, an ortho-, meta-, or para-substituted aryl bromide, a terminal olefin, and a base in DMF under the j...

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Bibliographic Details
Published in:Journal of the American Chemical Society 2004-01, Vol.126 (1), p.78-79
Main Authors: Faccini, Fiorenza, Motti, Elena, Catellani, Marta
Format: Article
Language:English
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Summary:Biphenylylalkenes containing an ortho substituent in one ring and a different ortho-, meta-, or para-substituent in the other are prepared in satisfactory yield from an ortho-substituted aryl iodide, an ortho-, meta-, or para-substituted aryl bromide, a terminal olefin, and a base in DMF under the joint catalytic action of palladium(0) and norbornene.
ISSN:0002-7863
1520-5126
DOI:10.1021/ja039043g